71144-09-7Relevant academic research and scientific papers
Triggering Lewis Acidic Nature through the Variation of Coordination Environment of Cd-Centers in 2D-Coordination Polymers
Kumar, Nikhil,Paul, Avijit Kumar
supporting information, p. 1284 - 1294 (2020/02/04)
The rational design and successful synthesis of novel functional metal-organic frameworks relies on careful selection of metals and versatile organic ligands. A newly designed pyrazole-based dicarboxylate ligand, 5-(3,5-dimethyl-1H-pyrazol-1-yl) 1,3-benze
Strecker reactions with hexacyanoferrates as non-toxic cyanide sources
Grundke, Caroline,Opatz, Till
supporting information, p. 2362 - 2366 (2019/05/17)
The Strecker reaction is the most widely applied three-component reaction. Although highly useful for the preparation of α-amino nitriles, α-amino acids, hydantoins and numerous related compounds, the need for the application of toxic sources of HCN limits its application in both academic and industrial settings. Here, we present a facile protocol for Strecker reactions using a mixture of potassium ferri- and ferrocyanides as a non-toxic substitute.
Alpha-cyanidation method of mono-alkyl substituted aniline
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Paragraph 0021-0101; 0102; 0103; 0104; 0105, (2017/09/13)
The invention discloses an alpha-cyanidation method of mono-alkyl substituted aniline. According to the method, various aromatic, aliphatic, and heterocycle substituted secondary amines of anilines are taken as the raw materials, trimethylsilyl cyanide is
Role of (3-aminopropyl)tri alkoxysilanes in grafting of chlorosulphonic acid immobilized magnetic nanoparticles and their application as heterogeneous catalysts for the green synthesis of α-aminonitriles
Singh, Harminder,Rajput, Jaspreet Kaur,Arora, Priya,Jigyasa
, p. 84658 - 84671 (2016/10/31)
The surface modification of SiO2 coated Fe3O4 nanoparticles by grafting silane coupling agents is a highly significant approach to enhancing the interface interaction between the inorganic magnetic core and the organic fun
Glycerol mediated strecker reaction: Catalyst-free protocol for the synthesis of α-amino nitriles
Ghogare, Ramesh S.,Rajeshwari,Narsaiah, A. Venkat
supporting information, p. 688 - 692 (2015/04/14)
Environmental friendly multicomponent protocol for the preparation of α-amino nitriles has been developed. In this methodology, glycerol was demonstrated as an efficient and alternative solvent for organic synthesis. After the reaction, glycerol was recov
Strecker-type reaction catalyzed by carboxylic acids in aqueous media
Xie, Zhengfeng,Li, Guilong,Zhao, Gang,Wang, Jide
experimental part, p. 2035 - 2039 (2009/12/27)
Carboxylic acid catalyzed Strecker-type reactions were successfully carried out by simply mixing aldehydes, amines, tributyltin cyanide and carboxylic acid in aqueous media at room temperature, to afford α-aminonitriles in high yields. Georg Thieme Verlag
Synthesis of Some New 3,4-Diarylsydnones
Csongar, Ch.,Mueller, I.,Slezak, H.,Klebsch, H.-J.,Tomaschewski, G.
, p. 1006 - 1014 (2007/10/02)
The synthesis of some new sydnones 4 is described.Their characteristic absorption maxima, mass spectroscopic fragmentation and C=O-valence vibrations are given.The sydnones 4 are synthezid by nitrosation of C,N-diarylglycines 3 (from strecker synthesis) a
