7143-42-2

Basic information

• Product Name: methyl 2-[(methoxycarbonyl)amino]benzoate
• CAS NO: 7143-42-2
• Molecular Formula: C₁₀H₁₁NO₄
• Molecular Weight: 209.1986
• Mol File: 7143-42-2.mol
• Article Data: 11

Chemical Properties

• Boiling Point: 274.2°C at 760 mmHg
• Flash Point: 119.6°C
• Density: 1.254g/cm³
• Vapor Pressure: 0.0055mmHg at 25°C
• Refractive Index: 1.561
• CAS DataBase Reference: methyl 2-[(methoxycarbonyl)amino]benzoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2-[(methoxycarbonyl)amino]benzoate(7143-42-2)
• EPA Substance Registry System: methyl 2-[(methoxycarbonyl)amino]benzoate(7143-42-2)

Safety Data

• Hazardous Substances Data: 7143-42-2(Hazardous Substances Data)

Upstream product

• 120-72-9 indole 
• 67-56-1 methanol 
• 2826-30-4 2-(2-nitrobenzylidene)malononitrile 
• 552-89-6 2-nitro-benzaldehyde 
• 109-77-3 malononitrile 
• 86451-26-5 2,2'-(phenyl-λ³-iodanediyl)bis(isoindoline-1,3-dione) 
• 136918-14-4 phthalimide 
• 29621-67-8 trans-N,N'-bis(phthalimido)diazene 
• 1793-07-3 methyl 2-isocyanatobenzoate 
• 160852-85-7 2-[2-(2-methoxyethoxy)ethoxy]ethyl methyl carbonate 
• 134-20-3 2-carbomethoxyaniline 
• 91-56-5 indole-2,3-dione 
• 2439-85-2 N-bromophthalimide 
• 3481-09-2 N-chlorophthalimide 

Downstream Products

• 118-92-3 anthranilic acid 
• 1207-75-6 2,4-Dioxo-3-(2-hydroxyethyl)-1,2,3,4-tetrahydroquinazoline 
• 6268-38-8 N-methoxycarbonyl-anthranilic acid 

Relevant articles and documents

Insight into the offbeat electrochemical methoxylation of isatin

A claim by Kazimierczuk and co-workers to have synthesized the diene 1 by electrochemical vic-dimethoxylation of isatin 2 is wrong. The product is now shown by a careful analysis of spectral data and synthesis to be in reality methyl N-(methoxycarbonyl)an

Tunable Electrosynthesis of Anthranilic Acid Derivatives via a C-C Bond Cleavage of Isatins

A facile and direct electrocatalytic C-C bond cleavage/functionalization reaction of isatins was developed. With isatins as the amino-attached C1 sources, a variety of aminobenzoates, and aminobenzamides were synthesized in moderate to good yields under mild conditions.

Beyond conventional routes, an unprecedented metal-free chemoselective synthesis of anthranilate esters via a multicomponent reaction (MCR) strategy

A hitherto unreported route for the synthesis of anthranilate esters is demonstrated using 2-nitrobenzaldehyde, malonitrile and an alcohol or amine via a metal and oxidant free multicomponent reaction (MCR) strategy. This process simultaneously installs an ester and urea or urethane functionality via CO and CN bond formations via concurrent oxidation of the aldehyde group and reduction of the nitro group involving an intramolecular redox process.