71581-92-5

Usage

Chemical Properties

white to light yellow crystal powde

InChI:InChI=1/C14H21NO/c16-11-13-8-4-5-9-14(13)15-10-12-6-2-1-3-7-12/h1-3,6-7,13-16H,4-5,8-11H2/p+1/t13-,14-/m0/s1

Upstream product

• 38778-78-8 ethyl 2-(benzylamino)cyclohex-1-ene-1-carboxylate 
• 16524-13-3 (+/-)-cis-2-benzoylamino-cyclohexane carboxylic acid 
• 63683-35-2 cis-2-benzylamino-1-cyclohexanecarboxylic acid 
• 63683-36-3 (1S,2R)-2-{[1-Phenyl-meth-(E)-ylidene]-amino}-cyclohexanecarboxylic acid 
• 71556-37-1 methyl cis-2-benzylideneiminocyclohexanecarboxylate 
• 16524-13-3 (+/-)-N-benzoyl-trans-2-aminocyclohexane-carboxylic acid 
• 71556-37-1 methyl trans-2-benzylideneiminocyclohexanecarboxylate 
• 14166-21-3 (+/-)-trans-1,2-cyclohexanedicarboxylic anhydride 
• 34314-73-3 C₁₁H₁₉NO₃Si 
• 40015-88-1 methyl trans-2-aminocyclohexanecarboxylate 
• 100-52-7 benzaldehyde 
• 13149-00-3 1,2-cis-cyclohexanedicarboxylic anhydride 
• 935-79-5 cis-1,2,3,6-tetrahydrophthalic anhydride 
• 34314-73-3 C₁₁H₁₉NO₃Si 

Downstream Products

• 107313-14-4 1-benzyl-1,4,4a,5,6,7,8,8a-octahydro-3,2,1-benzoxathiazine 2-oxide 
• 107313-14-4 1-benzyl-1,4,4a,5,6,7,8,8a-octahydro-3,2,1-benzoxathiazine 2-oxide 
• 117720-30-6 1-Benzyl-1-((1R,2S)-2-hydroxymethyl-cyclohexyl)-3-methyl-thiourea 
• 107313-14-4 1-benzyl-1,4,4a,5,6,7,8,8a-octahydro-3,2,1-benzoxathiazine 2-oxide 
• 107313-14-4 1-benzyl-1,4,4a,5,6,7,8,8a-octahydro-3,2,1-benzoxathiazine 2-oxide 
• 107313-20-2 (2S*,4aS*,8aS*)-1-benzyl-2-phenyl-1,4,4a,5,6,7,8,8a-octahydro-2H-3,1,2-benzoxazaphosphinine 2-oxide 
• 107313-20-2 (2R*,4aS*,8aS*)-1-benzyl-2-phenyl-1,4,4a,5,6,7,8,8a-octahydro-2H-3,1,2-benzoxazaphosphinine 2-oxide 
• 107313-20-2 (2R*,4aS*,8aR*)-1-benzyl-2-phenyl-1,4,4a,5,6,7,8,8a-octahydro-2H-3,1,2-benzoxazaphosphinine 2-oxide 
• 107313-20-2 (2S*,4aS*,8aR*)-1-benzyl-2-phenyl-1,4,4a,5,6,7,8,8a-octahydro-2H-3,1,2-benzoxazaphosphinine 2-oxide 
• 92597-09-6 cis-5-Benzyl-3-oxa-5-azabicyclo<4.4.0>decane 
• 213764-26-2 1-(R)-cis-2-aminocyclohexanemethanol 
• 117720-47-5 [(4aR,8aR)-1-Benzyl-octahydro-benzo[d][1,3]thiazin-(2Z)-ylidene]-methyl-amine 
• 117720-55-5 [(4aR,8aR)-1-Benzyl-octahydro-benzo[d][1,3]oxazin-(2Z)-ylidene]-methyl-amine 

Relevant academic research and scientific papers

Chirality control by substituents in the asymmetric addition of Et2Zn to aromatic aldehydes catalyzed by cis-(1R,2S)-2-benzamidocyclohexanecarboxylic acid derived 1,3-aminoalcohols

A series of novel optically active 1,3-aminoalcohols based on cis-(1R,2S)-2-benzamidocyclohexanecarboxylic acid and trans-(1R,2R)-2-benzamidocyclohexanecarboxylic acid were synthesized and used in the asymmetric diethylzinc addition to aromatic aldehydes.

Chemo- and diastereoselective reduction of β-enamino esters: A convenient synthesis of both cis- and trans-γ-amino alcohols and β-amino esters

Convenient procedures for the chemo- and diastereoselective reduction of b-enamino esters 1 are described. Both cis- and trans-γ-amino alcohols 2 or b-amino esters 3 can be prepared by reduction of b-enamino esters 1, readily available starting materials, with the use of inexpensive reagents Na/i-PrOH or NaHB(OAc)3/AcOH, respectively, and the appropriate reduction conditions. The mechanisms and diastereoselectivities for the reductions are discussed. The relative configurations and conformations of the diastereoisomeric γ-amino alcohols 2 and β-amino esters 3 obtained are established by 1H and 13C NMR study and unequivocally set by their cyclic derivatives tetrahydro-1,3-oxazines 4.

Preparations and Crystal Structures of the 2-Oxides of Some Octahydro-3,2,1-benzoxathiazines and Octahydro-2H-3,1,2-benzoxazaphosphorines

The cis- and trans-fused 1-benzyl-1,4,4a,5,6,7,8,8a-octahydro-3,2,1-benzoxathiazine 2-oxides and cis- and trans-fused 1-benzyl-2-phenyl-1,4,4a,5,6,7,8,8a-octahydro-2H-3,1,2-benzoxazaphosphorine 2-oxides have been prepared from the cis- and trans-2-benzylaminocyclohexanemethanols and their structures have been determined by n.m.r. and crystallographic methods.

STEREOCHEMICAL STUDIES-76 SATURATED HETEROCYCLES-63 SYNTHESIS OF CIS- AND TRANS-N-METHYL- AND N-BENZYL-4,5- AND 5,6-TETRAMETHYLENETETRAHYDRO-1,3-OXAZINES; AN X-RAY STUDY OF N-BENZYL-CIS-4,5-TETRAMETHYLENETETRAHYDRO-1,3-OXAZINIUM-PICRATE

The corresponding cis- and trans-N-methyl- and N-benzyl-5,6- and 4,5-tetramethylenetetrahydro-1,3-oxazines (5a,b-8a,b) were synthesized from cis- and trans-N-methyl- and N-benzyl-2-aminomethyl-1-cyclohexanols (1a,b,2 2a,b), and from cis- and trans-N-methy

STEREOCHEMICAL STUDIES XXXVIII SATURATED HETEROCYCLES, XIV; SYNTHESIS AND CONFORMATIONAL ANALYSIS OF STEREOISOMERIC CIS- AND TRANS-TETRAMETHYLENETETRAHYDRO-N-METHYL- AND -N-BENZYL-1,3-OXAZINES

Cis and trans-2-methylaminomethyl- and -benzylaminomethyl-1-cyclohexanol (1-4), as well as cis- and trans-2-hydroxymethyl-1-methylamino- and -benzylamino-cyclohexane (5-8) were allowed to react with p-nitrobenzaldehyde to yield 2-p-nitrophenyl-3-methyl- a