72474-39-6

Basic information

• Product Name: Benzene, 1-(1,2-diphenylethenyl)-4-methoxy-, (Z)-
• CAS NO: 72474-39-6
• Molecular Formula: C21H18O
• Molecular Weight: 286.373
• Mol File: 72474-39-6.mol
• Article Data: 49

Chemical Properties

• CAS DataBase Reference: Benzene, 1-(1,2-diphenylethenyl)-4-methoxy-, (Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-(1,2-diphenylethenyl)-4-methoxy-, (Z)-(72474-39-6)
• EPA Substance Registry System: Benzene, 1-(1,2-diphenylethenyl)-4-methoxy-, (Z)-(72474-39-6)

Safety Data

• Hazardous Substances Data: 72474-39-6(Hazardous Substances Data)

Upstream product

• 14382-03-7 1-(4-methoxy-phenyl)-1,2-diphenyl-ethanol 
• 93296-09-4 4-methoxyphenylzinc chloride 
• 119379-68-9 (E)-1,1'-(1-Iodo-1,2-ethenediyl)bisbenzene 
• 104-92-7 1-bromo-4-methoxy-benzene 
• 501-65-5 diphenyl acetylene 
• 696-62-8 para-iodoanisole 
• 75-97-8 3,3-dimethyl-butan-2-one 
• 41038-35-1 (E)-1-bromo-2-(4-methoxyphenyl)-1,2-diphenylethene 
• 94465-25-5 9-(4-methoxyphenyl)-9H-xanthen-9-ol 
• 108-86-1 bromobenzene 
• 768-60-5 4-methoxyphenylacetylen 
• 73183-34-3 bis(pinacol)diborane 
• 100-42-5 styrene 
• 530-48-3 1,1-Diphenylethylene 

Downstream Products

• 72474-41-0 cis-1,2-diphenyl-1-(p-hydroxyphenyl) ethylene 
• 41038-35-1 (E)-1-bromo-2-(4-methoxyphenyl)-1,2-diphenylethene 
• 50438-37-4 (E/Z)-1-bromo-2-(p-methoxyphenyl)-1,2-diphenylethene 
• 34288-92-1 (Z)-1-(4-methoxyphenyl)-1,2-diphenyl-3,3,3-trifluoropropene 
• 36029-60-4 (E)-3,3,3-trifluoro-1-(4-methoxyphenyl)-1,2-diphenylpropene 
• 1417821-09-0 C₂₂H₁₉F₃O₂ 
• 857906-52-6 1,2-diphenyl-2-(4-methoxyphenyl)vinyl bromide 
• 879008-28-3 3c-(4-methoxy-phenyl)-2,3t-diphenyl-acrylic acid 
• 846541-57-9 3t-(4-methoxy-phenyl)-2,3c-diphenyl-acrylic acid 
• 17932-18-2 3-(4-methoxyphenyl)-2-phenyl-1H-inden-1-one 
• 70603-19-9 6-methoxy-2,3-diphenyl-1H-inden-1-one 
• 97800-39-0 cis-1,2-diphenyl-1-<4-(2-diethylaminoethoxy)phenyl>ethylene 
• 30222-34-5 (-)-(1-(4-methoxyphenyl)ethane-1,2-diyl)dibenzene 
• 72474-42-1 (Z)-(1-chloro-2-(4-methoxyphenyl)ethene-1,2-diyl)dibenzene 

Relevant articles and documents

Pd-Catalyzed Coupling of N-Tosylhydrazones with Benzylic Phosphates: Toward the Synthesis of Di- or Tri-Substituted Alkenes

This study shows that various di- and tri-substituted alkenes with high chemoselectivity were obtained in good to high yields by coupling N-tosylhydrazones (NTHs) with benzylic phosphates as electrophilic partners. The obtained new catalytic system consis

Oxime ligands for Pd catalysis of the Mizoroki–Heck reaction, Suzuki–Miyaura coupling & annulation reactions

Monodentate and bidentate chelating oximes are readily available ligands for the Pd catalysis of the Mizoroki–Heck reaction and the Suzuki coupling. High yields were obtained in the Suzuki coupling in aqueous dioxane with TBABr as additive. The oximes can be easily synthesized from the corresponding ketones or aldehydes and thus provide a very large number of nitrogen-based ligands. They have the advantage of not undergoing oxidative degradation, common for phosphine ligands. Chelating oximes with Pd(OAc)2, activate aryl iodides to give high yields of the substitution products in the Mizoroki–Heck reactions as well as the Suzuki coupling. Acetophenone oxime ligand with Pd(OAc)2, catalyzed the reaction of aryl iodides with 1,2-disubstituted alkenes in moderate to high yields. As a test example, the LaRock indole annulation and synthesis of isocoumarin were achieved with acetophenone oxime ligand and Pd(OAc)2 in high yields.

Polysubstituted ethylene compound as well as preparation method and application thereof

The invention discloses a polysubstituted ethylene compound as well as a preparation method and application thereof. The invention particularly discloses a preparation method of a polysubstituted ethylene compound as shown in a formula III, which comprises the following step: in an organic solvent, carrying out reaction as shown in the specification on a compound as shown in a formula I and a compound as shown in a formula II in the presence of a palladium catalyst, a phosphine ligand and alkali to obtain the polysubstituted ethylene compound as shown in the formula III. The preparation methodcan be suitable for various types of substrates, and the configuration of double bonds is controllable.