7334-52-3Relevant articles and documents
Neighboring-Group Participation in the Gas Phase. Loss of Benzaldehyde from dialkylsilyl-Substituted 1,3-Dithianes
Faessler, Juerg,Huber, Priska,Bratovanov, Svetoslav,Bigler, Laurent,Bild, Norbert,Bienz, Stefan
, p. 1855 - 1862 (1995)
dialkylsilyl-substituted 1,3-dithianes show in CI-MS an abundant loss of benzaldehyde from the (1+) quasi-molecular ion.The fragmentation is explained with an intramolecular redox process, where a hydride is proposed to be transfer
Ethyl lactate mediated thioacetalization of aldehydes at ambient temperature
Wan, Jie-Ping,Jing, Yanfeng,Liu, Yunyun
, p. 1302 - 1305 (2016/09/28)
Dithioacetalization reactions of aldehydes with thiols/thiophenols have been successfully achieved at room temperature by employing the green, bio-based ethyl lactate as the reaction medium. By means of this sustainable approach, a class of dithioacetals has been acquired with high diversity and efficiency.
Visible-light-promoted conversion of alkyl benzyl ether to alkyl ester or alcohol via O-α-sp3 C-H cleavage
Lu, Ping,Hou, Tianyuan,Gu, Xiangyong,Li, Pixu
, p. 1954 - 1957 (2015/04/27)
A mild and high-yielding visible-light-promoted conversion of alkyl benzyl ethers to the alkyl esters or alkyl alcohols was developed. Mechanistic studies provided evidence for a radical chain reaction involving the homolytic cleavage of O-α-sp3 C-H bonds in the substrate as one of the propagation steps. We propose that α-bromoethers are key intermediates in the transformation.