936-63-0Relevant articles and documents
Ynamide-Mediated Thionoester and Dithioester Syntheses
Yao, Chaochao,Yang, Jinhua,Lu, Xiaobiao,Zhang, Shuyu,Zhao, Junfeng
, p. 6628 - 6631 (2020/09/02)
A novel ynamide-mediated synthesis of thionoesters and dithioesters is described. The selective addition reactions of various monothiocarboxylic acids with ynamide furnish α-thioacyloxyenamides, which undergo transesterification with nucleophilic -OH or -SH species to afford thionoesters and dithioesters, respectively. The broad substrate scope, mild reaction conditions, and excellent yields make this method an attractive synthetic approach to thionoesters and dithioesters.
The Endocyclic Restriction Test: An Investigation of the Geometries of Thiophilic Additions of Aryl Radicals and Aryllithium Reagents to Dithioesteres
Beak, Peter,Park, Yong Sun,Reif, Lee A.,Liu, Chao
, p. 7410 - 7413 (2007/10/02)
Prospective thiophilic additions of aryl radicals and aryllithium reagents in four-, six-, eight-, and 15-membered endocyclic rings have been investigated for the radical and organolithium intermediates generated from the dithioesteres 8-11.These reaction
Reduction of Thionoesters to Ethers by Triorganotin Hydrides
Smith, Colin,Tunstad, Linda M.,Gutierrez, Carlos G.
, p. 257 - 260 (2007/10/02)
Esters 1 are efficiently deoxygenated to the corresponding ethers 3 in two steps by first conversion to the thionoesters 2 and subsequent reduction of these by triorganotin hydrides.