73351-21-0

Basic information

• Product Name: 4-(((4-methoxyphenyl)amino)methyl)phenol
• Synonyms: 4-(((4-methoxyphenyl)amino)methyl)phenol
• CAS NO: 73351-21-0
• Molecular Weight: 229.279
• Mol File: 73351-21-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 4-(((4-methoxyphenyl)amino)methyl)phenol(CAS DataBase Reference)
• NIST Chemistry Reference: 4-(((4-methoxyphenyl)amino)methyl)phenol(73351-21-0)
• EPA Substance Registry System: 4-(((4-methoxyphenyl)amino)methyl)phenol(73351-21-0)

Safety Data

• Hazardous Substances Data: 73351-21-0(Hazardous Substances Data)

Upstream product

• 623-05-2 (4-hydroxyphenyl)methanol 
• 104-94-9 4-methoxy-aniline 
• 2101-87-3 p-methoxy-phenylazide 
• 1375004-98-0 4′-vinyl-4-hydroxystilbene 
• 1370449-08-3 2',4',6'-trimethyl-4-hydroxystilbene 
• 537-42-8 3,5-dimethoxy-4'-hydroxy-trans-stilbene 
• 18951-47-8 (E)-4-<2-(3-chlorophenyl)ethenyl>phenol 
• 65819-34-3 (E)-4-hydroxy-4'-methoxystilbene 
• 677353-68-3 (E)-4-tert-butyl-4'-hydroxystilbene 
• 18951-45-6 (E)-1-(4-hydroxy)phenyl-2-(4-methyl)phenylethene 
• 136827-57-1 4-[(E)-2-(4-hydroxyphenyl)ethenyl]benzonitrile 
• 14064-83-6 trans-4-hydroxy-4'-nitrostilbene 
• 18951-46-7 (E)-4-<2-(4-chlorophenyl)ethenyl>phenol 
• 6554-98-9 trans-4-Hydroxystilbene 

Relevant articles and documents

Hydrogen-Free Cobalt-Rhodium Heterobimetallic Nanoparticle-Catalyzed Reductive Amination of Aldehydes and Ketones with Amines and Nitroarenes in the Presence of Carbon Monoxide and Water

Cobalt-rhodium heterobimetallic nanoparticle-catalyzed reductive amination of aldehydes and ketones with amines in the presence of 5 atm carbon monoxide without an external hydrogen source has been developed. Water added and generated in situ produces hydrogen via a water-gas-shift reaction. The reaction can be extended to the tandem reduction of aldehydes and ketones with nitroarenes. The catalytic system is stable under the reaction conditions and could be reused eight times without losing any catalytic activity. (Chemical Equation Presented).

A process for preparing amine compound using carbon-supported cobalt-rhodium nanoparticel catalyzed hydrogen-free recuctive amination

The present invention relates to hydrogen-free reductive amination of an aldehyde and/or ketone and an amine and/or nitroarene using cobalt-rhodium heterometal nanoparticles supported on carbon as a non-homogeneous catalyst. According to the present invention, it is possible to carry out amination under significantly lower pressure as compared to the reductive amination carried out in the presence of a conventional rhodium or ruthenium catalyst. In addition, there is no need for using an additional ligand, acid or base. Further, it is possible to use water generated in a reaction system by a water-gas shift reaction as a hydrogen source with no use of an external hydrogen source, and thus to use a solvent without purification. Thus, it is possible to simplify the reaction procedure. The catalyst system according to the present invention provides a simple method for preparing secondary and tertiary amines from various aldehydes and amines.