73814-79-6

Upstream product

• 63930-46-1 (S)-3-benzyloxy-2-methylpropan-1-ol 
• 81470-75-9 (Z)-(R)-5-Benzyloxy-4-methyl-pent-2-enoic acid methyl ester 
• 81470-72-6 (R)-ethyl (Z)-5-benzyloxy-4-methyl-2-pentenoate 
• 81470-74-8 (R)-5-Benzyloxy-4-methyl-pent-2-ynoic acid methyl ester 
• 81520-06-1 ((R)-4,4-Dibromo-2-methyl-but-3-enyloxymethyl)-benzene 
• 81470-71-5 ((S)-3-tert-Butoxy-2-methyl-propoxymethyl)-benzene 
• 100-39-0 benzyl bromide 
• 63930-49-4 (R)-3-(benzyloxy)-2-methylpropan-1-ol 
• 128442-96-6 (2S),(Z)-5-benzyloxy-1,2-epoxy-3-pentene 
• 79027-28-4 (2S)-3-(benzyloxy)-2-methylpropanal 
• 75-16-1 methylmagnesium bromide 
• 917-54-4 methyllithium 
• 128442-95-5 (S,E)-2-(3-(benzyloxy)prop-1-enyl)oxirane 

Downstream Products

• 88367-70-8 (2R,3R,4R)-5-Benzyloxy-4-methyl-pentane-1,2,3-triol 
• 73814-75-2 (2R,3S,4S)-5-benzyloxy-2,3-epoxy-4-methyl-1-pentanol 
• 73814-75-2 [(2R,3S)-3-((S)-2-Benzyloxy-1-methyl-ethyl)-oxiranyl]-methanol 
• 73814-75-2 [(2S,3S)-3-((R)-2-Benzyloxy-1-methyl-ethyl)-oxiranyl]-methanol 
• 155430-47-0 (E)-3-[(2R,3R)-3-((1R,2S,3S)-4-Benzyloxy-2-hydroxy-1,3-dimethyl-butyl)-oxiranyl]-acrylic acid ethyl ester 
• 155613-08-4 (E)-(4S,5S,6S,7S,8S)-9-Benzyloxy-5,7-dihydroxy-4,6,8-trimethyl-non-2-enoic acid ethyl ester 
• 155430-49-2 (E)-3-[(2S,3S)-3-((1R,2R,3R,4S,5S)-6-Benzyloxy-2,4-dihydroxy-1,3,5-trimethyl-hexyl)-oxiranyl]-acrylic acid ethyl ester 
• 155430-50-5 (E)-(4R,5R,6S,7S,8R,9S,10S)-11-Benzyloxy-5,7,9-trihydroxy-4,6,8,10-tetramethyl-undec-2-enoic acid ethyl ester 
• 155430-46-9 (E)-3-[(2R,3R)-3-((1S,2S,3S)-4-Benzyloxy-1,3-dimethyl-2-triethylsilanyloxy-butyl)-oxiranyl]-acrylic acid ethyl ester 

Relevant academic research and scientific papers

Total synthesis of scytophycin C. 1. Stereoselective syntheses of the C(1)-C(18) segment and the C(19)-C(31) segment

[Equation presented] Stereoselective total synthesis of scytophycin C, a marine 22-membered macrolide displaying potent activity against a variety of human carcinoma cell lines, has been reported in which the polypropionate structure bearing contiguous as

Synthetic Studies on Polypropionate Antibiotics Based on the Stereospecific Methylation of γ,δ-Epoxy Acrylates by Trimethylaluminum. A Highly Stereoselective Construction of the Eight Contiguous Chiral Centers of Ansa-chains of Rifamycins

A highly stereoselective construction of the eight contiguous chiral centers of ansa-chains of rifamycins has been accomplished by the iterative use of the stereospecific methylation of γ,δ-epoxy acrylates by trimethylaluminum which was recently developed

STEREOSELECTIVE SN2' ADDITIONS OF ORGANOCUPRATES TO HOMOCHIRAL ACYLIC VINYLOXIRANES

Additions of various methylcopper reagents to the homochiral acylic vinyloxiranes A14, A15, B6-B9, and C5, C6 were performed in order to evaluate E/Z and syn/anti preferences.The unsubstituted oxiranes A14 and A15 gave a mixture of SN2 and SN2' substitution products with the four reagents examined, LiMe2Cu, LiMeCuCN, BrMgMe2Cu, and LiMeCuI*BF3.The more highly substituted systems B6-B9 derived from geraniol and C5, C6 derived from nerol yielded only SN2' products.The (Z)-allylic alcohol derivatives B8 and C6 and LiMeCuCN gave the best anti/syn ratios (99:1 and 97:3, respectively).In both cases the newly formed double bond was exclusively E.