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Cis-2,6-bis(phenylmethyl)cyclohexanone is an organic compound with the molecular formula C21H22O. It is a white crystalline solid that is characterized by its unique molecular structure, featuring a cyclohexanone ring with two phenylmethyl groups attached at the 2 and 6 positions in a cis configuration. cis-2,6-bis(phenylmethyl)cyclohexanone is known for its potential applications in the synthesis of various pharmaceuticals and agrochemicals due to its ability to act as a chiral building block. The cis-isomer is particularly important as it can provide a specific stereochemistry that is often required in the development of enantiomerically pure compounds. The compound's properties, such as its melting point and solubility, can be influenced by the cis arrangement of the phenylmethyl groups, making it a subject of interest in organic chemistry and pharmaceutical research.

7382-09-4

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7382-09-4 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 7382-09-4 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 7,3,8 and 2 respectively; the second part has 2 digits, 0 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 7382-09:
(6*7)+(5*3)+(4*8)+(3*2)+(2*0)+(1*9)=104
104 % 10 = 4
So 7382-09-4 is a valid CAS Registry Number.

7382-09-4Relevant academic research and scientific papers

Short synthesis of (+)-cylindricine C by using a catalytic asymmetric Michael reaction with a two-center organocatalyst

Shibuguchi, Tomoyuki,Mihara, Hisashi,Kuramochi, Akiyoshi,Sakuraba, Shun,Ohshima, Takashi,Shibasaki, Masakatsu

, p. 4635 - 4637 (2007/10/03)

(Chemical Equation Presented) Two for the price of one: The total synthesis of (+)-cylindricine C has been achieved in six steps using a catalytic asymmetric Michael reaction and tandem cyclization. A newly designed two-center organocatalyst gives good selectivity in this Michael reaction. TaDiAS = tartrate-derived diammonium salt.

α-Benzylation of Ketones by Reaction with Benzylamine. Regioselective Reduction of C-C Double Bonds in Cohjugated Enones

Armesto, Diego,Esteban, Soledad,Horspool, William M.,Martin, Juan-Antonio F.,Martinez-Alcazar, Paz,Perez-Ossorio, Rafael

, p. 751 - 755 (2007/10/02)

Prolonged reaction of some ketones with benzylamine at reflux converts them into α-benzyl derivatives by a route involving Aldol condensation of the related ketimine with benzaldimine followed by exclusive reduction of the resultant C-C double bond.Reduction does not occur when pure benzylamine is used under oxygen-free nitrogen, however the inclusion of a trace of benzaldehyde restores the efficiency of the reaction.Treatment of several ketones in this manner established the scope of the process.When the reaction was extended to the reduction of α,β-unsaturated enones again using benzylamine, reaction times were shorter and the product yield greater.The possibility that the reductive step was an intramolecular 1,5-hydrogen transfer was studied.

SELECTIVE REDUCTION OF C-C DOUBLE BONDS IN CONJUGATED ENONES BY BENZYLAMINE. A VARIANT OF THE SOMMELET REACTION

Armesto, Diego,Horspool, William M.,Martin, Juan Antonio F.,Perez-Ossorio, Rafael

, p. 5217 - 5220 (2007/10/02)

Prolonged reaction of some ketones with benzylamine at reflux converts them into α-benzyl derivatives by a route involving aldol condensation of the related ketimine with benzaldimine followed by exclusive reduction of the resultant C-C double bond by hydride transfer from benzylamine.This efficient procedure is a variant of the Sommelet reaction for the synthesis of aldehydes.

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