7382-10-7Relevant articles and documents
Alkylation of enolates with triflates.
Bates, Robert B.,Taylor, Stuart R.
, p. 4469 - 4470 (2007/10/02)
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SELECTIVE REDUCTION OF C-C DOUBLE BONDS IN CONJUGATED ENONES BY BENZYLAMINE. A VARIANT OF THE SOMMELET REACTION
Armesto, Diego,Horspool, William M.,Martin, Juan Antonio F.,Perez-Ossorio, Rafael
, p. 5217 - 5220 (2007/10/02)
Prolonged reaction of some ketones with benzylamine at reflux converts them into α-benzyl derivatives by a route involving aldol condensation of the related ketimine with benzaldimine followed by exclusive reduction of the resultant C-C double bond by hydride transfer from benzylamine.This efficient procedure is a variant of the Sommelet reaction for the synthesis of aldehydes.