74422-05-2

Basic information

• Product Name: 1H-Cyclobut[b]indole-1-carboxylic acid, 3-benzoyl-2,2a,3,7b-tetrahydro-, methyl ester
• CAS NO: 74422-05-2
• Molecular Formula: C19H17NO3
• Molecular Weight: 307.349
• Mol File: 74422-05-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1H-Cyclobut[b]indole-1-carboxylic acid, 3-benzoyl-2,2a,3,7b-tetrahydro-, methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 1H-Cyclobut[b]indole-1-carboxylic acid, 3-benzoyl-2,2a,3,7b-tetrahydro-, methyl ester(74422-05-2)
• EPA Substance Registry System: 1H-Cyclobut[b]indole-1-carboxylic acid, 3-benzoyl-2,2a,3,7b-tetrahydro-, methyl ester(74422-05-2)

Safety Data

• Hazardous Substances Data: 74422-05-2(Hazardous Substances Data)

Upstream product

• 90539-97-2 methyl exo-3-benzoyl-7b-methylthio-1,2,2a,7b-tetrahydro-3H-cyclobutindole-1-carboxylate 
• 40015-10-9 3-methylthioindole 
• 90539-83-6 1-benzoyl-3-methylthioindole 
• 98-88-4 benzoyl chloride 
• 74422-11-0 cis-exo-3-benzoyl-1,2,2a,7b-tetrahydro-3H-cyclobutindole-1-carboxylic acid 
• 74422-06-3 cis-3-benzoyl-2a,7b-dihydro-3H-cyclobutindole 
• 74422-10-9 1-benzoyl-1H-1-benzazepine 
• 1496-76-0 N-benzoylindole 
• 292638-85-8 acrylic acid methyl ester 
• 186581-53-3 diazomethane 

Downstream Products

• 76077-46-8 cis-3-cyclohexylcarbonyl-2a,7b-dihydro-3H-cyclobut-indole 
• 76056-11-6 1-cyclohexylcarbonyl-1H-benzazepine 
• 80998-63-6 cyclohexyl(1H-indol-1-yl)methanone 
• 74422-10-9 1-benzoyl-1H-1-benzazepine 
• 74422-08-5 cis-3-benzyl-2a,7b-dihydro-3H-cyclobutindole 
• 634-42-4 N-1-naphthalenyl-benzamide 
• 1496-76-0 N-benzoylindole 
• 576-15-8 N-acetylindole 
• 81851-43-6 cis-3-benzoyl-1-methyl-2a,7b-dihydrocyclobutindole 
• 74422-06-3 cis-3-benzoyl-2a,7b-dihydro-3H-cyclobutindole 
• 76056-14-9 1-benzyl-1H-1-benzazepine 
• 1150-91-0 1-benzoyl-2,3,4,5-tetrahydro-1H-1-benzazepine 
• 74422-11-0 cis-exo-3-benzoyl-1,2,2a,7b-tetrahydro-3H-cyclobutindole-1-carboxylic acid 

Relevant articles and documents

Regio- and Stereo-chemical Aspects of Photocycloaddition Between 1-Benzoylindoles and Olefins

The regio- and stereo-selectivities in the photocycloaddition of a series of 1-benzoylindoles with vinyl acetate and methyl acrylate have been investigated.With some exceptions, the 1-benzoylindoles gave exclusively or predominatly the corresponding 1-acetoxy-3-benzoyl and 3-benzoyl-1-methoxycarbonyl-1,2,2a,7b-tetrahydro-3H-cyclobutindoles as mixtures of stereoisomers.

SYNTHESIS AND SOME PROPERTIES OF 1H-1-BENZAZEPINES

1H-1-Benzazepines were synthesized by thermal ring opening of 2a, 7b-dihydrocyclobutindoles.The thermal and photochemical behavior of the 1H-1-benzazepines is also described.