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N,N',1,2-Tetraphenylethane-1,2-bisimine is an organic compound with the chemical formula C34H26N2. It is a derivative of ethylenediamine, featuring two phenyl groups attached to each nitrogen atom and two additional phenyl groups attached to the carbon atoms at the 1 and 2 positions. N,N',1,2-Tetraphenylethane-1,2-bisimine is known for its rigid structure and is often used in the synthesis of various organic compounds, particularly those with conjugated systems. It is also utilized in the preparation of ligands for coordination chemistry and as a building block in the construction of more complex molecular architectures. The compound's unique structure and properties make it a valuable tool in the field of organic chemistry and materials science.

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  • 7510-33-0 Structure
  • Basic information

    1. Product Name: N,N',1,2-Tetraphenylethane-1,2-bisimine
    2. Synonyms: 1,2,N,N'-Tetraphenylethane-1,2-diimine;N,N'-(1,2-Diphenyl-1,2-ethanediylidene)bisaniline;N,N'-(1,2-Diphenyl-1,2-ethanediylidene)bisbenzenamine;N,N'-(1,2-Diphenylethanediylidene)bis(aniline);N,N',1,2-Tetraphenylethane-1,2-bisimine;N,N'-Diphenyl-1,2-diphenylethane-1,2-diimine
    3. CAS NO:7510-33-0
    4. Molecular Formula: C26H20N2
    5. Molecular Weight: 360.4504
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 7510-33-0.mol
  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: 522.9°Cat760mmHg
    3. Flash Point: 263.2°C
    4. Appearance: /
    5. Density: 1.04g/cm3
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: N,N',1,2-Tetraphenylethane-1,2-bisimine(CAS DataBase Reference)
    10. NIST Chemistry Reference: N,N',1,2-Tetraphenylethane-1,2-bisimine(7510-33-0)
    11. EPA Substance Registry System: N,N',1,2-Tetraphenylethane-1,2-bisimine(7510-33-0)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 7510-33-0(Hazardous Substances Data)

7510-33-0 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 7510-33-0 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 7,5,1 and 0 respectively; the second part has 2 digits, 3 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 7510-33:
(6*7)+(5*5)+(4*1)+(3*0)+(2*3)+(1*3)=80
80 % 10 = 0
So 7510-33-0 is a valid CAS Registry Number.

7510-33-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name N,N',1,2-Tetraphenylethane-1,2-bisimine

1.2 Other means of identification

Product number -
Other names N,N'-Diphenyl-1,2-diphenylethane-1,2-diimine

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:7510-33-0 SDS

7510-33-0Relevant articles and documents

α-Diimine synthesis via titanium-mediated multicomponent diimination of alkynes with C-nitrosos

Cheng, Yukun,Egger, Dominic T.,Frye, Connor W.,Kounalis, Errikos,Pearce, Adam J.,Tonks, Ian A.

, p. 1469 - 1477 (2022/02/11)

α-Diimines are commonly used as supporting ligands for a variety of transition metal-catalyzed processes, most notably in α-olefin polymerization. They are also precursors to valuable synthetic targets, such as chiral 1,2-diamines. Their synthesis is usually performed through acid-catalyzed condensation of amines with α-diketones. Despite the simplicity of this approach, accessing unsymmetrical α-diimines is challenging. Herein, we report the Ti-mediated intermolecular diimination of alkynes to afford a variety of symmetrical and unsymmetrical α-diimines through the reaction of diazatitanacyclohexadiene intermediates with C-nitrosos. These diazatitanacycles can be readily accessed in situ via the multicomponent coupling of TiNR imidos with alkynes and nitriles. The formation of α-diimines is achieved through formal [4 + 2]-cycloaddition of the C-nitroso to the Ti and γ-carbon of the diazatitanacyclohexadiene followed by two subsequent cycloreversion steps to eliminate nitrile and afford the α-diimine and a Ti oxo.

White-Fluorescent Dual-Emission Mechanosensitive Membrane Probes that Function by Bending Rather than Twisting

Humeniuk, Heorhii V.,Rosspeintner, Arnulf,Licari, Giuseppe,Kilin, Vasyl,Bonacina, Luigi,Vauthey, Eric,Sakai, Naomi,Matile, Stefan

supporting information, p. 10559 - 10563 (2018/08/17)

Bent N,N′-diphenyl-dihydrodibenzo[a,c]phenazine amphiphiles are introduced as mechanosensitive membrane probes that operate by an unprecedented mechanism, namely, unbending in the excited state as opposed to the previously reported untwisting in the ground and twisting in the excited state. Their dual emission from bent or “closed” and planarized or “open” excited states is shown to discriminate between micelles in water and monomers in solid-ordered (So), liquid-disordered (Ld) and bulk membranes. The dual-emission spectra cover enough of the visible range to produce vesicles that emit white light with ratiometrically encoded information. Strategies to improve the bent mechanophores with expanded π systems and auxochromes are reported, and compatibility with imaging of membrane domains in giant unilamellar vesicles by two-photon excitation fluorescence (TPEF) microscopy is demonstrated.

A Highly Stereoselective Metal-Free Hydrogenation of Diimines for the Synthesis of Cis -Vicinal Diamines

Zhu, Xiaxia,Du, Haifeng

supporting information, p. 3106 - 3109 (2015/06/30)

A highly stereoselective metal-free hydrogenation of vicinal diimines has been successfully realized for the first time using 5-10 mol % of Piers borane as a catalyst under mild conditions, and a variety of cis-1,2-diamines were obtained in 92-99% yields.

In vitro bacteriostatic and DNA interaction studies of drug-based mixed-ligand complexes of cobalt(II)

Patel, Mohan,Chhasatia, Mehul,Bhatt, Bhupesh

experimental part, p. 220 - 230 (2012/03/10)

The dinuclear cobalt(II) complexes with ciprofloxacin and bidentate ligands were synthesized and characterized using infrared spectra, electronic spectra, magnetic measurements, elemental analyses, thermal investigation, and mass spectroscopy. Here in we

Antibacterial and DNA interaction studies of zinc(II) complexes with quinolone family member, ciprofloxacin

Patel, Mohan,Chhasatia, Mehul,Parmar, Pradhuman

experimental part, p. 439 - 446 (2010/04/02)

DNA binding and cleavage characteristics of Zn(II) complexes have been investigated. The DNA interaction property of the complexes has been investigated using absorption spectra, viscosity measurements, as well as gel electrophoresis studies. Intrinsic bi

Electronically tunable N-heterocyclic carbene ligands: 1,3-diaryl vs. 4,5-diaryl substitution

Ogle, James W.,Miller, Stephen A.

scheme or table, p. 5728 - 5730 (2010/01/31)

The catalytic activity of iridium-mediated transfer hydrogenation is readily tuned by electronic variation of the ligated tetraaryl-N-heterocyclic carbene and the installation of electron donating groups on the N-aryl substituents is more important than o

Synthesis of electronically diverse tetraarylimidazolylidene carbenes via catalytic aldimine coupling

Ogle, James W.,Zhang, Jubo,Reibenspies, Joseph H.,Abboud, Khalil A.,Miller, Stephen A.

supporting information; experimental part, p. 3677 - 3680 (2009/07/01)

(Chemical Equation Presented) A new method for synthesizing symmetrical N-heterocyclic imidazolium salts is described. Catalytic coupling of aldimines with cyanide followed by oxidation gives α-diketimines, which can then be cyclized with formaldehyde in

Microwave-assisted efficient synthesis of diimines in dry media using silica gel supported sodium hydrogen sulfate as reusable solid support

Bazgir, Ayoob

, p. 1 - 2 (2007/10/03)

A simple and efficient method for synthesis of diimines using silica gel supported sodium hydrogen sulfate as reusable solid support in solvent-free conditions under microwave irradiation is described.

A novel decyanogenative coupling of α-cyanoimines mediated by samarium. A facile route to α-diketimines

Thakur, Ashim J.,Prajapati, Dipak,Sandhu, Jagir S.

, p. 102 - 103 (2007/10/03)

Conversion of α-cyanoimines 1 into α-diketimines 2 has been achieved successfully by using samarium diiodide in dry tetrahydrofuran in high yields without formation of anilinoanil 3, 1,2-diamines 4 or anilides 5.

Formation of benzil diimines by microwave-assisted reaction of benzil with aromatic amines on alumina surface without solvent

Singh,Mahajan

, p. 410 - 411 (2007/10/03)

The microwave-assisted solvent-free reaction of benzil with aromatic amines (in 1 : 2 molar ratio) on an alumina surface for 4 min affords benzil diimines (1,2,3,4-tetraaryl-1,4-diaza-1,3-butadienes).

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