75366-33-5

Usage

Uses

Used in Plastics and Polymers Industry:
(1-cyclopentylvinyl)benzene is used as a monomer for the production of polystyrene and other copolymers. Its role in this application is to provide a structural backbone that contributes to the formation of durable and versatile plastic materials, which are widely used in various consumer and industrial products.
Used in Chemical Synthesis:
(1-cyclopentylvinyl)benzene is utilized as a starting material in the synthesis of other organic compounds. Its reactivity and structural features make it a valuable intermediate in the creation of specialty chemicals and complex organic molecules.
Used in Adhesives and Resins Production:
As a component in the production of specialty chemicals, (1-cyclopentylvinyl)benzene is also used in the formulation of adhesives and resins. Its presence in these materials enhances their adhesive and binding properties, making them suitable for a range of applications, from construction to automotive industries.
Safety and Precautions:
Due to its potential health and environmental hazards, (1-cyclopentylvinyl)benzene is typically handled and used in industrial settings with proper safety measures. Workers and handlers are advised to follow safety protocols to minimize exposure and ensure the safe and effective use of this chemical compound.

Upstream product

• 23985-40-2 tricyclopentylborane 
• 76886-55-0 Acetophenone 2,4,6-triisopropylbenzenesulphonyl hydrazone 
• 56771-29-0 <1-(4-Pentenyl)>triphenylphosphonium bromide 
• 98-86-2 acetophenone 
• 5422-88-8 phenyl cyclopentyl ketone 
• 1779-49-3 Methyltriphenylphosphonium bromide 

Downstream Products

• 183201-49-2 (R)-α-phenyl-α-cyclopentyl-α-hydroxyethanol 
• 183201-50-5 (S)-1-Cyclopentyl-1-phenyl-ethane-1,2-diol 
• 54321-44-7 1-cyclopentyl-2-phenylethanone 
• 1669-76-7 3-cyclopentyl-1,3-diphenylpropan-1-one 
• 175343-28-9 2-cyclopentyl-2-phenylethan-1-amine 

Relevant academic research and scientific papers

Visible-Light-Induced Meerwein Fluoroarylation of Styrenes

An unprecedented approach for assembling a broad range of 1,2-diarylethane derivatives with fluorine-containing fully substituted carbon centers was developed. The protocol features straightforward operation, proceeds under metal-free condition, and accommodates a large variety of synthetically useful functionalities. The critical aspect to the success of this novel transformation lies in using aryldiazonium salts as both aryl radical progenitor and also as single electron acceptor which elegantly enables a radical-polar crossover manifold.

Electrochemical fluorosulfonylation of styrenes

An environmentally friendly and efficient electrochemical fluorosulfonylation of styrenes has been developed. With the use of sulfonylhydrazides and triethylamine trihydrofluoride, a diverse array of β-fluorosulfones could be readily obtained. This reaction features mild conditions and a broad substrate scope, which could also be conveniently extended to a gram-scale preparation.

Electrochemistry enabled selective vicinal fluorosulfenylation and fluorosulfoxidation of alkenes

Both sulfur and fluorine play important roles in organic synthesis, the life science, and materials science. The direct incorporation of these elements into organic scaffolds with precise control of the oxidation states of sulfur moieties is of great significance. Herein, we report the highly selective electrochemical vicinal fluorosulfenylation and fluorosulfoxidation reactions of alkenes, which were enabled by the unique ability of electrochemistry to dial in the potentials on demand. Preliminary mechanistic investigations revealed that the fluorosulfenylation reaction proceeded through a radical-polar crossover mechanism involving a key episulfonium ion intermediate. Subsequent electrochemical oxidation of fluorosulfides to fluorosulfoxides were readily achieved under a higher applied potential with the adventitious H2O in the reaction mixture.

The Allylic Acetoxylation of 1,1-Disubstituted Alkenes Catalyzed by a Palladium(II)/Monothiadiazole Ligand System

A palladium(II)/monothiadiazole ligand catalytic system and its application in catalyzing the acetoxylation of 1,1-disubstituted alkenes have been developed. With this newly designed monothiadiazole thioether ligand, the reaction showed a broad scope with respect to 1,1-disubstituted olefins, giving the corresponding products in yields of 30-86percent.

Synthesis of Functionalized α-Vinyl Aldehydes from Enaminones

An efficient RhII-catalyzed synthesis of functionalized α-vinyl aldehydes with high E/Z stereoselectivity was developed. The reaction mediates the cyclopropanation of enaminones with vinyl carbenoids that are generated from cyclopropenes in situ to give the aminocyclopropane intermediates. Selective C?C bond cleavage of the cyclopropane intermediates leads to formation of α-vinyl aldehyde derivatives with high E/Z selectivity. This method proceeds at room temperature under very mild reaction conditions and works with a broad substrate scope.

Regioselective Transfer Hydrodeuteration of Alkenes with a Hydrogen Deuteride Surrogate Using B(C6F5)3 Catalysis

A regioselective hydrodeuteration of alkenes using monodeuterated cyclohexa-1,4-dienes as surrogates for hydrogen deuteride (HD) gas is reported. The metal-free process proceeds under B(C6F5)3 catalysis presumably by deuteride abstraction to form borodeuteride [DB(C6F5)3]a and highly Br?nsted-acidic Wheland intermediates. Low catalyst loadings (2.5 mol %) are used, and the reaction proceeds at room temperature.

Transformation of 1,5- and 1,6-dienes to carbocycles by hydrozirconation and oxidation with cerium(IV) compounds

Cyclopentane and cyclohexane derivatives are prepared from 1,5- and 1,6-dienes in a one pot procedure by hydrozirconation, then oxidation of the generated 5- and 6-alkenylzirconocene chlorides with ammonium hexanitratocerate.

The reaction of iodine with vinyltrialkylborates derived from trialkylboranes and trisylhydrazones of methyl ketones. A new method for synthesis of 1,1-dialkylethenes

1,1-Dialkylethenes are readily prepared in good yields from vinyltrialkylborates derived from trialkylboranes and trisylhydrazones of methyl ketones by treatment with iodine.