7570-91-4

Basic information

• Product Name: Benzene, 1,3,5-trimethyl-2-(methylthio)-
• CAS NO: 7570-91-4
• Molecular Formula: C10H14S
• Molecular Weight: 166.287
• Mol File: 7570-91-4.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: Benzene, 1,3,5-trimethyl-2-(methylthio)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,3,5-trimethyl-2-(methylthio)-(7570-91-4)
• EPA Substance Registry System: Benzene, 1,3,5-trimethyl-2-(methylthio)-(7570-91-4)

Safety Data

• Hazardous Substances Data: 7570-91-4(Hazardous Substances Data)

Upstream product

• 191227-60-8 C₂₁H₂₁O₂PS 
• 74-88-4 methyl iodide 
• 773-64-8 2-mesitylenesulphonyl chloride 
• 616-38-6 carbonic acid dimethyl ester 
• 1541-10-2 mesitylthiol 
• 67-56-1 methanol 
• 55757-31-8 1,3,5-trimethyl-4-thiocyanatobenzene 
• 624-92-0 Dimethyldisulphide 
• 108-67-8 1,3,5-trimethyl-benzene 
• 931-88-4 cis-Cyclooctene 
• 4028-63-1 iodomesitylene 
• 127-09-3 sodium acetate 

Downstream Products

• 1251955-03-9 C₁₁H₁₄F₃NO₂S₂ 
• 50418-78-5 (-)-(R)-S-(2-Mesityl)-S-methyl-sulfoximin 
• 18689-86-6 (R)-methyl mesityl sulfoxide 
• 82079-40-1 (S)-(2,4,6)-trimethylphenyl methyl sulfoxide 
• 6462-31-3 methyl 2,4,6-trimethylphenyl sulfone 
• 7321-59-7 1,3,5-trimethyl-2-(methylsulfinyl)benzene 

Relevant articles and documents

Copper-Catalyzed Methylthiolation of Aryl Iodides and Bromides with Dimethyl Disulfide in Water

An efficient route to aryl methyl sulfides through the copper-catalyzed coupling reaction of aryl iodides or bromides with dimethyl disulfide in water is described. Electron-donating and electron-withdrawing functional groups in the substrates were tolerated, and the corresponding products were obtained in moderate to good yields.

Enantioselective copper catalysed intramolecular C-H insertion reactions of α-diazo-β-keto sulfones, α-diazo-β-keto phosphine oxides and 2-diazo-1,3-diketones; the influence of the carbene substituent

Enantioselectivities in C-H insertion reactions, employing the copper-bis(oxazoline)-NaBARF catalyst system, leading to cyclopentanones are highest with sulfonyl substituents on the carbene carbon, and furthermore, the impact is enhanced by increased steric demand on the sulfonyl substituent (up to 91%ee). Enantioselective intramolecular C-H insertion reactions of α-diazo-β-keto phosphine oxides and 2-diazo-1,3-diketones are reported for the first time.