75735-31-8

Basic information

• Product Name: E-O-phenylbenzaldoxime
• Synonyms: E-O-phenylbenzaldoxime
• CAS NO: 75735-31-8
• Molecular Weight: 197.236
• Mol File: 75735-31-8.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: E-O-phenylbenzaldoxime(CAS DataBase Reference)
• NIST Chemistry Reference: E-O-phenylbenzaldoxime(75735-31-8)
• EPA Substance Registry System: E-O-phenylbenzaldoxime(75735-31-8)

Safety Data

• Hazardous Substances Data: 75735-31-8(Hazardous Substances Data)

Upstream product

• 591-50-4 iodobenzene 
• 932-90-1 Benzaldoxime 
• 455-19-6 4-Trifluoromethylbenzaldehyde 
• 1948-40-9 4-hydroxy-3,5-diiodobenzaldehyde 
• 2973-77-5 3,5-dibromo-4-hydroxybenzaldehyde 
• 4846-21-3 O-phenylhydroxylamine 
• 10203-08-4 3,5-dichlorobenzaldehyde 
• 447-61-0 2-Trifluoromethylbenzaldehyde 
• 619-21-6 m-formylphenyl benzoic acid 
• 454-89-7 3-Trifluoromethylbenzaldehyde 
• 99907-98-9 O-(3-(trifluoromethyl)phenyl)hydroxylamine 
• 32085-88-4 3,5-difluorobenzaldehyde 
• 83-38-5 2,6-dichlorobenzaldehyde 
• 100-52-7 benzaldehyde 

Downstream Products

• 76570-67-7 Phenoxybenzamine 
• 100-47-0 benzonitrile 
• 3229-70-7 phenolate 
• 76570-73-5 N-Benzyl-N-phenoxy-benzamide 

Relevant articles and documents

Cul-mediated cross-coupling of aryl halides with oximes: A direct access to O-aryloximes

The first Cu-catalyzed cross-coupling of aromatic oximes and haloarenes is reported. This one-step formation of the =N-O-Ar linkage gives access to a range of oxime ethers in good to moderate yields.

Studies on the Preparation of N-Alkyl-O-phenylhydroxylamines

Several possible routes to the title compounds have been investigated.The reaction of N-hydroxycarbamates (1) with diphenyliodonium bromide gave, unexpectedly, N-hydroxy-N-phenylcarbamates (2), while N-methyl-N-hydroxycarbamates (6) gave 2-(N-methyl-N-alkoxycarbonylamino)phenols (7).Mechanistic aspects of the N-arylations and subsequent rearrangements are discussed.The desired N-alkyl-O-phenylhydroxylamines were obtained by the reduction of O-phenyloximes (15) with sodium cyanoborohydride.