7631-42-7Relevant articles and documents
Design and evolution of an enzyme with a non-canonical organocatalytic mechanism
Burke, Ashleigh J.,Lovelock, Sarah L.,Frese, Amina,Crawshaw, Rebecca,Ortmayer, Mary,Dunstan, Mark,Levy, Colin,Green, Anthony P.
, p. 219 - 223 (2019/10/21)
The combination of computational design and laboratory evolution is a powerful and potentially versatile strategy for the development of enzymes with new functions1–4. However, the limited functionality presented by the genetic code restricts t
Degenerate transesteriflcation of dimeric lithium 2,4,6-trimethylphenolate and a further observation on the reaction of tetramers
Jackman, Lloyd M.,Chen, Xian
, p. 8681 - 8684 (2007/10/03)
The rates of exchange of the 2,4,6-trimethylphenolate ion between dimeric lithium 2,4,6-trimethylphenolate-d9 and a series of 2,4,6-trimethylphenyl esters [2,4,6-(CH3)3C6H2COOCH2R; R = CHs
Electrochemical Reduction of Carbon Dioxide Using Iron-Sulfur Clusters as Catalyst Precursors
Nakazawa, Makoto,Mizobe, Yasushi,Matsumoto, Yoichi,Uchida, Yasuzo,Tezuka, Meguru,Hidai, Masanobu
, p. 809 - 814 (2007/10/02)
The potential-current relationships of DMF solutions of a series of iron-sulfur compounds have revealed that in the presence of clusters 2- (R=PhCH2 or But) and 3- (M=Mo or W) the electroreduction of CO2 proceeds at the potential shifted by about 0.7 and 0.5 V, respectively, to the positive direction compared to the potential at which CO2 is reduced without any catalyst.When controlled potential electrolysis of a DMF solution containing 2- was carried out under CO2 at -2.0 V vs.SCE, phenylacetate and formate were formed as the products resulting from CO2 reduction.The cubane structure of this cluster collapsed rapidly under these conditions.However, when excess amount of PhCH2SH was added to the catholyte, the cluster structure was preserved during a relatively long period of electrolysis, and the yield of phenylacetate increased but that of formate decreased compared with the reaction in the absence of free PhCH2SH.
