76634-95-2

Basic information

• Product Name: 3-CHLORO-2-TRIMETHYLSILOXYPROPENE
• Synonyms: 3-Chloro-2-trimethylsilyloxy-1-propene
• CAS NO: 76634-95-2
• Molecular Formula: C₆H₁₃ClOSi
• Molecular Weight: 164.71
• Mol File: 76634-95-2.mol
• Article Data: 5

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 3-CHLORO-2-TRIMETHYLSILOXYPROPENE(CAS DataBase Reference)
• NIST Chemistry Reference: 3-CHLORO-2-TRIMETHYLSILOXYPROPENE(76634-95-2)
• EPA Substance Registry System: 3-CHLORO-2-TRIMETHYLSILOXYPROPENE(76634-95-2)

Safety Data

• Hazardous Substances Data: 76634-95-2(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 78-95-5 chloroacetone 
• 16029-98-4 trimethylsilyl iodide 
• 71482-65-0 3-chloro-1-trimethylsilyl-2-propanone 
• 1833-53-0 2-(Trimethylsilyloxy)propene 
• 128-09-6 N-chloro-succinimide 

Downstream Products

• 110-43-0 n-pentyl methyl ketone 
• 72009-05-3 2-Methyl-6-(2-oxopropyl)cyclohexanone 
• 27943-50-6 2-methyl-2-(2-oxopropyl)cyclohexanone 
• 6126-53-0 2-(2-oxopropyl)cyclohexanone 
• 61154-45-8 2-(2-oxopropyl)cycloheptan-1-one 
• 7018-92-0 2,5-Undecanedione 
• 59021-31-7 2-trimethylsilyloxy-3-phenyl-1-propene 
• 103-79-7 1-phenyl-acetone 
• 105302-65-6 Pt(η(2)-CH2C(O)CH2)(PPh3)2 
• 1112-67-0 tetrabutyl-ammonium chloride 
• 23193-18-2 diethyl 2-(2-oxopropyl)malonate 
• 62981-80-0 cyano-2-oxo-4-pentanoate d'ethyle 
• 110-13-4 2,5-hexanedione 
• 583-05-1 1-phenylpentane-1,4-dione 

Relevant articles and documents

AN EFFICIENT REGIO AND STEREOSELECTIVE SYNTHESIS OF SILYL ENOL ETHERS

Ketones and aldehydes on treatment with NaBr-Me3SiCl-Et3N in DMF at ambient temperature yield silyl enol ethers with high regio- and stereoselectivity.

A CONVENIENT PREPARATION METHOD OF THE VINYLIC HALIDE ISOMER OF CHLOROTRIMETHYLSILYL ENOL ETHERS

Reaction of trimethylsilyliodide (generated in situ from trimethylsilylchloride and sodium iodide) in the presence of triethylamine in acetonitrile with α-chloroketones yields the vinylic halide isomer of chlorotrimethylsilyl enol ethers.

Alkylation and arylation of 2-trimethylsiloxyallyl halides. A new regiospecific route to silyl enol ethers

Alkylation and arylation of 2-trimethylsiloxyallyl halides with lithium dialkyl- and diarylcuprate, respectively, gave silyl enol ethers in a regiospecific manner.