7693-30-3

Basic information

• Product Name: 4-chlorobenzyl phenyl sulfide
• Synonyms: 4-chlorobenzyl phenyl sulfide
• CAS NO: 7693-30-3
• Molecular Formula: C₁₃H₁₁ClS
• Molecular Weight: 234.74444
• Mol File: 7693-30-3.mol
• Article Data: 21

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 4-chlorobenzyl phenyl sulfide(CAS DataBase Reference)
• NIST Chemistry Reference: 4-chlorobenzyl phenyl sulfide(7693-30-3)
• EPA Substance Registry System: 4-chlorobenzyl phenyl sulfide(7693-30-3)

Safety Data

• Hazardous Substances Data: 7693-30-3(Hazardous Substances Data)

Upstream product

• 930-69-8 sodium thiophenolate 
• 104-83-6 1-Chloro-4-(chloromethyl)benzene 
• 108-98-5 thiophenol 
• 931-59-9 benzenesulfenyl chloride 
• 622-95-7 4-chlorobenzyl bromide 
• 14204-24-1 N-(phenylthio)succinimide 
• 106-43-4 para-chlorotoluene 
• 42766-37-0 C₈H₆ClO₂^(1-)*K⁽¹⁺⁾ 
• 882-33-7 diphenyldisulfane 
• 15184-98-2 N,N-dimethyl-4-chlorobenzylamine 
• 100-68-5 methyl-phenyl-thioether 
• 1878-66-6 4-chlorophenylacetic Acid 
• 4551-15-9 phenylthiotrimethylsilane 
• 14856-74-7 4-chlorobenzyltrimethylsilyl ether 

Downstream Products

• 81157-18-8 1--4-chlorobenzene 
• 57058-33-0 N-(4-chlorobenzyl)acetamide 
• 41037-80-3 (α-Brom-4-chlor-benzyl)-phenyl-sulfon 
• 7693-37-0 <4,α-Dichlor-benzyl>-phenyl-sulfon 
• 17530-80-2 1-chloro-4-((phenylsulfinyl)methyl)benzene 
• 51229-56-2 1-chloro-4-((phenylsulfonyl)methyl)benzene 
• 352-12-5 4-chlorobenzyl fluoride 

Relevant articles and documents

Photocatalytic synthesis method of aryl thioether and derivatives thereof

The invention belongs to the field of organic synthesis, and particularly relates to a photocatalytic synthesis method of aryl thioether and derivatives thereof. The synthesis method comprises the steps: dissolving an N-(sulfanyl) amide compound into a methyl aromatic compound under the protection of inert gas, and thus obtaining the aryl thioether compound under the action of light, a catalyst, aligand and alkali. According to the method, the coupling reaction of a C-S bond is completed through visible light induction by utilizing a light/Ni dual-catalytic system, so that the method has goodfunctional group compatibility, and the C-S bond compound can be selectively and efficiently constructed in one step. The method has the advantages of simple catalytic system, mild reaction conditions, economical, simple and easily available substrate, simple reaction operation and the like.

Transition metal-free coupling reactions of benzylic trimethylammonium salts with di(hetero)aryl disulfides and diselenides

A new protocol was developed to synthesize (enantioenriched) thioethers and selenoethers from (chiral) benzylic trimethylammonium salts and di(hetero)aryl disulfides or diselenides. These syntheses were promoted by the presence of weak base and did not require the use of any transition metal, and resulted in the target products with good to excellent yields (72-94%). Using quaternary ammonium salts synthesized from enantiomerically enriched amines led to highly enantiopure benzylic thioethers and selenoethers (94-99% ee) with configurations reversed from those of their enantioenriched quaternary ammonium salts. This journal is

Alkyl Sulfides as Promising Sulfur Sources: Metal-Free Synthesis of Aryl Alkyl Sulfides and Dialkyl Sulfides by Transalkylation of Simple Sulfides with Alkyl Halides

A site-selective metal-free dealkylative approach to synthesize aryl alkyl and symmetrical dialkyl sulfides has been developed. This procedure is convenient and has wide functional group tolerance giving rise to sulfides carrying various alkyl chains from simple alkyl sulfides and alkyl halides in good to excellent yields. This transalkylation proceeds by an ionic mechanism via sulfonium intermediates and it was proposed that dimethylacetamide (DMAC) may participate in part to promote the reaction.