775-24-6Relevant articles and documents
Visible-Light-Induced Nickel-Catalyzed Cross-Coupling with Alkylzirconocenes from Unactivated Alkenes
Bai, Songlin,Gao, Yadong,Jiang, Chao,Liu, Xiaolei,Qi, Xiangbing,Wang, Jing,Wu, Qingcui,Yang, Chao
supporting information, p. 675 - 688 (2020/03/11)
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Rhodium-catalyzed silylation and intramolecular arylation of nitriles via the silicon-assisted cleavage of carbon-cyano bonds
Tobisu, Mamoru,Kita, Yusuke,Ano, Yusuke,Chatani, Naoto
supporting information; experimental part, p. 15982 - 15989 (2009/05/16)
A rhodium-catalyzed silylation reaction of carbon - cyano bonds using disilane has been developed. Under these catalytic conditions, carbon-cyano bonds in aryl, alkenyl, allyl, and benzyl cyanides bearing a variety of functional groups can be silylated. The observation of an enamine side product in the silylation of benzyl cyanides and related stoichiometric studies indicate that the carbon-cyano bond cleavage proceeds through the deinsertion of silyl isocyanide from η2-iminoacyl complex B. Knowledge gained from these studies has led to the development of a new intramolecular biaryl coupling reaction in which aryl cyanides and aryl chlorides are cross-coupled.
Study of the mechanism of the addition of benzyl bromide to trimethylvinylsilane in the presence of the Fe(CO)5-DMF system
Terent'ev, A. B.,Gapusenko, S. I.,Vasil'eva, T. T.
, p. 1352 - 1356 (2007/10/02)
The general kinetics of the addition of benzyl bromide to trimethylvinylsilane in the presence of the Fe(CO)5-DMF system has been studied.The reaction orders with respect to each reagent found in the study corresponding to a radical chain mechanism of the process.The metal-complex system takes part only in the initiation stage and only at a strictly defined ratio of the components. - Key words: benzyl bromide, trimethylvinylsilane, addition; radicals; metal-complex initiation; kinetics; mechanism.
