7783-26-8Relevant articles and documents
Unusually selective synthesis of chlorohydrooligosilanes
Lainer, Thomas,Fischer, Roland,Leypold, Mario,Holthausen, Michael,Wunnicke, Odo,Haas, Michael,Stueger, Harald
supporting information, p. 13812 - 13815 (2020/11/18)
New pathways towards molecular chlorohydrooligosilanes enable their one-pot synthesis in preparative amounts either by the selective chlorination of the corresponding perhydrosilanes with HCl/AlCl3 or by the partial hydrogenation of perchlorooligosilanes
Synthesis of polysilanes by tunneling reactions of H atoms with solid Si2H6 at 10K
Sogoshi, Norihito,Sato, Shoji,Takashima, Hideaki,Sato, Tetsuya,Hiraoka, Kenzo
, p. 986 - 987 (2012/09/22)
Tunneling reactions of H atoms with solid Si2H6 at 10K were investigated. The in situ and real-time reactions H + Si 2H6 to form silane and polysilanes were monitored using FT-IR. Quantitative analysis of gaseou
Diagnostics of the gas-phase thermal decomposition of Si2H6 using vacuum ultraviolet photoionization
Tonokura, Kenichi,Murasaki, Tetsuya,Koshi, Mitsuo
, p. 507 - 511 (2008/10/08)
Vacuum ultraviolet (VUV) photoionization at 10.2 eV was employed for the detection of gas-phase molecules formed after thermal decomposition of disilane at a total pressure of 30 Torr and in the temperature range of 298-740 K. The SinH2(n+1) (n=3-5) and SinH2n (n=2-5) species resulting from disilane pyrolysis in a flow reactor were directly observed using time-of-flight mass spectrometry. Unlike multiphoton ionization at 6.4 eV photons, no fragmentation was observed by the VUV single-photon ionization at 10.2 eV.
