79567-15-0

Basic information

• Product Name: 4,4'-di((E)-styryl)-1,1'-biphenyl
• Synonyms: 4,4'-di((E)-styryl)-1,1'-biphenyl
• CAS NO: 79567-15-0
• Molecular Weight: 358.483
• Mol File: 79567-15-0.mol

Chemical Properties

• CAS DataBase Reference: 4,4'-di((E)-styryl)-1,1'-biphenyl(CAS DataBase Reference)
• NIST Chemistry Reference: 4,4'-di((E)-styryl)-1,1'-biphenyl(79567-15-0)
• EPA Substance Registry System: 4,4'-di((E)-styryl)-1,1'-biphenyl(79567-15-0)

Safety Data

• Hazardous Substances Data: 79567-15-0(Hazardous Substances Data)

Upstream product

• 66-98-8 4,4'-diformylbiphenyl 
• 1100-88-5 benzyltriphenylphosphonium chloride 
• 1224-56-2 tributylbenzylphosphonium chloride 
• 100-52-7 benzaldehyde 
• 1667-10-3 4,4'-bis(chloromethyl)biphenyl 
• 106835-92-1 4,4'-Bis<(triphenylphosphonio)methyl>biphenyl-dibromid 
• 20248-86-6 4-4'-bis(bromomethyl)biphenyl 
• 1667-12-5 4,4'-bis(hydroxymethyl)biphenyl 
• 613-33-2 (4,4'-dimethyl-1,1'-biphenyl) 
• 538-51-2 benzylidene phenylamine 
• 100-42-5 styrene 
• 92-86-4 4-(4-bromophenyl)bromobenzene 

Relevant articles and documents

Synthesis, structure and catalysis of a NHC-Pd(II) complex based on a tetradentate mixed ligand

Bis-benzimidazolium salt (S)-2,2′-bis[2′′-(N-picolyl-benzimidazoliumyl)ethoxy]-1,1′-binaphthyl hexafluorophosphate [(S)-LH2]·(PF6)2 and its NHC palladium(ii) complex [(S)-LPd](PF6)2 (1) have been prepared and characterized. Complex 1 is formed by one tetradentate mixed ligand (S)-L and one Pd(ii) ion, in which one 15-membered ring and two 6-membered rings are present. In this complex, intramolecular π-π interactions between naphthalene rings and benzimidazole rings are observed. Additionally, the catalytic activity of complex 1 in three types of C-C coupling reactions (Suzuki-Miyaura, Heck-Mizoroki and Sonogashira reactions) was investigated. The results show that complex 1 is an effective catalyst in these coupling reactions.

Catalytic activities of NHC-PdCl2 species based on functionalized tetradentate imidazolium salt in three types of C-C coupling reactions

A functionalized tetradentate imidazolium salt 9,10-bis{di[2′-(N-ethylimidazolium-1-yl)ethyl]aminomethyl}anthracene tetrakis(hexafluorophosphate) (1) has been synthesized and characterized. The catalytic activity of the NHC-PdCl2 species formed by compound 1 and PdCl2 was tested in Suzuki-Miyaura, Heck-Mizoroki and Sonogashira reactions. The results showed that this catalytic system was effective for above three types of C-C coupling reactions.

Substituent effect on the photochemical and photophysical properties of 4,4′-distyrylbiphenyl derivatives

Photochemical properties of 4,4′-distyrylbiphenyl (DSBP) derivatives have been studied. While the introduction of methoxy groups at meta-positions does not influence the photoisomerization of DSBP, the introduction of methyl substituents at the biphenyl moiety (MDSBP) changed the photoisomerization from one-way cis-to-trans photoisomerization for DSBP to cistrans mutual photoisomerization for MDSBP.

Dendritic effect on the photoisomerization of 4,4′-distyrylbiphenyl in aqueous solution

Newly synthesized 4,4′-distyrylbiphenyl-cored water-soluble dendrimers underwent trans-to-cis photoisomerization, while the core 4,4′-distyrylbiphenyl underwent cis-to-trans one-way photoisomerization.

Wittig Reactions of Phosphoniomethylaryl Compounds with Sulfonated Aromatic and Heteroaromatic Aldehydes

Bis(triphenylphosphoniomethyl)aryl dichloride derivatives react with aromatic or heteroaromatic aldehydes which have a sulfonic or carboxylic group attached to the ring system, to yield stilbene compounds of a betaine-type structure.These betaines are reacted further with various aromatic or heteroaromatic aldehydes yielding asymmetrically substituted derivatives in excellent yields.This new method is widely applicable to the preparation of water-soluble, fluorescent whitening agents of the bis-stilbene type.