81386-30-3

Basic information

• Product Name: Sodium perchlorate hydrate
• Synonyms: 5-METHYL-3-(PARA-TOLYL)-1,2,4-OXADIAZOLE
• CAS NO: 81386-30-3
• Molecular Formula: C₁₀H₁₀N₂O
• Molecular Weight: 174.2
• Mol File: 81386-30-3.mol
• Article Data: 16

Chemical Properties

• Boiling Point: 293.4 °C at 760 mmHg
• Flash Point: 130.2 °C
• Appearance: /
• Density: 1.113 g/cm³
• Vapor Pressure: 0.00303mmHg at 25°C
• Refractive Index: 1.538
• CAS DataBase Reference: Sodium perchlorate hydrate(CAS DataBase Reference)
• NIST Chemistry Reference: Sodium perchlorate hydrate(81386-30-3)
• EPA Substance Registry System: Sodium perchlorate hydrate(81386-30-3)

Safety Data

• Hazardous Substances Data: 81386-30-3(Hazardous Substances Data)

Usage

General Description

Sodium perchlorate hydrate is a chemical compound consisting of sodium, perchlorate, and water molecules. It is commonly used as an oxidizing agent in various industrial processes, as well as in the manufacture of explosives, fireworks, and rocket propellants. The compound is highly soluble in water and forms stable solutions, making it useful in electroplating and etching applications. Sodium perchlorate hydrate is also utilized in laboratory research, particularly in the field of chemistry and material science. The hydrate form indicates that the compound contains a specific number of water molecules within its structure, which can affect its physical and chemical properties. Overall, sodium perchlorate hydrate is a versatile chemical with a wide range of applications in various industries and research fields.

InChI:InChI=1/C10H10N2O/c1-7-3-5-9(6-4-7)10-11-8(2)13-12-10/h3-6H,1-2H3

Upstream product

• 110449-27-9 5-acetonyl-3-(p-tolyl)-1,2,4-oxadiazole 
• 104-87-0 4-methyl-benzaldehyde 
• 64-19-7 acetic acid 
• 3717-15-5 p-methylbenzaldehyde oxime 
• 75-05-8 acetonitrile 
• 2033-24-1 cycl-isopropylidene malonate 
• 19227-13-5 p-toluamidoxime 
• 104-85-8 para-methylbenzonitrile 
• 923023-83-0 4-methylbenzamide oxime 
• 141-78-6 ethyl acetate 
• 79-20-9 acetic acid methyl ester 
• 540-88-5 acetic acid tert-butyl ester 
• 1895006-01-5 dimesityl(trifluoromethyl)sulfonium trifluoromethanesulfonate 
• 256956-42-0 3-[4-(bromomethyl)phenyl]-5-methyl-1,2,4-oxadiazole 

Downstream Products

• 855387-20-1 3-(p-tolyl-[1,2,4]oxadiazol-5-yl)-pyruvic acid ethyl ester 
• 588-46-5 N-(phenylmethyl)acetamide 
• 780-25-6 N-benzylidene benzylamine 
• 104-85-8 para-methylbenzonitrile 
• 116204-77-4 N-benzyl-4-methylbenzenecarboximidamide 
• 140-11-4 Benzyl acetate 
• 30377-13-0 2-methyl-4,6-di-p-tolyl-1,3,5-triazine 
• 5467-99-2 4-methylbenzoic acid benzyl ester 
• 7753-06-2 2-phenyl-4,6-di(4-methylphenyl)-1,3,5-triazine 
• 95124-68-8 5-methyl-3-(4-carboxyphenyl)-1,2,4-oxadiazole 

Relevant articles and documents

Potassium Poly(Heptazine Imide): Transition Metal-Free Solid-State Triplet Sensitizer in Cascade Energy Transfer and [3+2]-cycloadditions

Polymeric carbon nitride materials have been used in numerous light-to-energy conversion applications ranging from photocatalysis to optoelectronics. For a new application and modelling, we first refined the crystal structure of potassium poly(heptazine imide) (K-PHI)—a benchmark carbon nitride material in photocatalysis—by means of X-ray powder diffraction and transmission electron microscopy. Using the crystal structure of K-PHI, periodic DFT calculations were performed to calculate the density-of-states (DOS) and localize intra band states (IBS). IBS were found to be responsible for the enhanced K-PHI absorption in the near IR region, to serve as electron traps, and to be useful in energy transfer reactions. Once excited with visible light, carbon nitrides, in addition to the direct recombination, can also undergo singlet–triplet intersystem crossing. We utilized the K-PHI centered triplet excited states to trigger a cascade of energy transfer reactions and, in turn, to sensitize, for example, singlet oxygen (1O2) as a starting point to synthesis up to 25 different N-rich heterocycles.

One-Pot Synthesis of 3,5-Disubstituted 1,2,4-Oxadiazoles Using Catalytic System NaOH?DMSO

One-pot convenient process was developed for the production of 3,5-disubstituted 1,2,4-oxadiazoles by reaction of amidoximes with anhydrides or acyl chlorides in a system NaOH?DMSO. The reaction proceeds at room temperature with high yields.

Cobalt(III)-Catalyzed Oxadiazole-Directed C-H Activation for the Synthesis of 1-Aminoisoquinolines

Aromatic heterocycles have been identified as effective directing groups (DGs) in C-H functionalization but can be retained as undesired bulky substituents in the final products. Herein, we report a Co(III)-catalyzed 1-aminoisoquinoline synthesis strategy based on oxadiazole-directed aromatic C-H coupling with alkynes and a subsequent redox-neutral C-N cyclization reaction. This labile N-O bond-based protocol has allowed the toleration of a broad range of functional groups.