81386-30-3

Usage

Uses

Used in Oxidizing Agent Applications:
Sodium perchlorate hydrate is used as an oxidizing agent in various industrial processes due to its high reactivity and ability to release oxygen. It is particularly effective in the manufacture of explosives, fireworks, and rocket propellants, where its oxidizing properties enhance the combustion and energy release of the materials.
Used in Electroplating and Etching Applications:
In the electroplating industry, sodium perchlorate hydrate is utilized as a solution component to improve the quality and uniformity of the plated layers. Its stable solutions facilitate the deposition of metals onto various surfaces, enhancing the durability and appearance of the final product. Additionally, in etching applications, the compound aids in the selective removal of material from surfaces, creating intricate patterns and designs.
Used in Laboratory Research:
Sodium perchlorate hydrate is widely used in laboratory research, especially in the fields of chemistry and material science. Its unique properties make it an essential reagent for various experiments and analyses. Researchers leverage its oxidizing capabilities and solubility to study chemical reactions, material synthesis, and other scientific phenomena.
Used in Aerospace Industry:
In the aerospace industry, sodium perchlorate hydrate is used as a key component in rocket propellants. Its high energy release and oxidizing properties contribute to the efficient combustion of rocket fuels, enabling the generation of thrust required for space exploration and satellite launches.
Used in Fireworks Industry:
Sodium perchlorate hydrate is used in the fireworks industry to enhance the brightness and intensity of pyrotechnic displays. Its oxidizing properties enable the production of vibrant colors and effects, creating visually stunning and memorable events.

InChI:InChI=1/C10H10N2O/c1-7-3-5-9(6-4-7)10-11-8(2)13-12-10/h3-6H,1-2H3

Upstream product

• 110449-27-9 5-acetonyl-3-(p-tolyl)-1,2,4-oxadiazole 
• 3235-02-7 p-methylbenzaldehyde oxime 
• 35787-71-4 thianthrene cation radical perchlorate 
• 19227-13-5 (Z)-N'-hydroxy-4-methylbenzimidamide 
• 104-87-0 4-methyl-benzaldehyde 
• 64-19-7 acetic acid 
• 110449-19-9 p-toluamide O-(α-acetylacetoacetyl)oxime 
• 19227-13-5 p-toluamidoxime 
• 75-36-5 acetyl chloride 
• 1895006-01-5 dimesityl(trifluoromethyl)sulfonium trifluoromethanesulfonate 
• 256956-42-0 3-[4-(bromomethyl)phenyl]-5-methyl-1,2,4-oxadiazole 
• 540-88-5 acetic acid tert-butyl ester 
• 79-20-9 acetic acid methyl ester 
• 141-78-6 ethyl acetate 

Downstream Products

• 855387-20-1 3-(p-tolyl-[1,2,4]oxadiazol-5-yl)-pyruvic acid ethyl ester 
• 588-46-5 N-(phenylmethyl)acetamide 
• 780-25-6 N-benzylidene benzylamine 
• 104-85-8 para-methylbenzonitrile 
• 116204-77-4 N-benzyl-4-methylbenzenecarboximidamide 
• 140-11-4 Benzyl acetate 
• 30377-13-0 2-methyl-4,6-di-p-tolyl-1,3,5-triazine 
• 5467-99-2 4-methylbenzoic acid benzyl ester 
• 7753-06-2 2-phenyl-4,6-di(4-methylphenyl)-1,3,5-triazine 
• 95124-68-8 5-methyl-3-(4-carboxyphenyl)-1,2,4-oxadiazole 

Relevant academic research and scientific papers

Potassium Poly(Heptazine Imide): Transition Metal-Free Solid-State Triplet Sensitizer in Cascade Energy Transfer and [3+2]-cycloadditions

Polymeric carbon nitride materials have been used in numerous light-to-energy conversion applications ranging from photocatalysis to optoelectronics. For a new application and modelling, we first refined the crystal structure of potassium poly(heptazine imide) (K-PHI)—a benchmark carbon nitride material in photocatalysis—by means of X-ray powder diffraction and transmission electron microscopy. Using the crystal structure of K-PHI, periodic DFT calculations were performed to calculate the density-of-states (DOS) and localize intra band states (IBS). IBS were found to be responsible for the enhanced K-PHI absorption in the near IR region, to serve as electron traps, and to be useful in energy transfer reactions. Once excited with visible light, carbon nitrides, in addition to the direct recombination, can also undergo singlet–triplet intersystem crossing. We utilized the K-PHI centered triplet excited states to trigger a cascade of energy transfer reactions and, in turn, to sensitize, for example, singlet oxygen (1O2) as a starting point to synthesis up to 25 different N-rich heterocycles.

Copper-Catalyzed Trifluoromethylation of Alkyl Bromides

Copper oxidative addition into organohalides is a challenging two-electron process. In contrast, formal oxidative addition of copper to C sp2 carbon-bromine bonds can be accomplished by employing latent silyl radicals under photoredox conditions. This novel paradigm for copper oxidative addition has now been applied to a Cu-catalyzed cross-coupling of C sp3-bromides. Specifically, a copper/photoredox dual catalytic system for the coupling of alkyl bromides with trifluoromethyl groups is presented. This operationally simple and robust protocol successfully converts a variety of alkyl, allyl, benzyl, and heterobenzyl bromides into the corresponding alkyl trifluoromethanes.

One-Pot Synthesis of 3,5-Disubstituted 1,2,4-Oxadiazoles Using Catalytic System NaOH?DMSO

One-pot convenient process was developed for the production of 3,5-disubstituted 1,2,4-oxadiazoles by reaction of amidoximes with anhydrides or acyl chlorides in a system NaOH?DMSO. The reaction proceeds at room temperature with high yields.

Cobalt(III)-Catalyzed Oxadiazole-Directed C-H Activation for the Synthesis of 1-Aminoisoquinolines

Aromatic heterocycles have been identified as effective directing groups (DGs) in C-H functionalization but can be retained as undesired bulky substituents in the final products. Herein, we report a Co(III)-catalyzed 1-aminoisoquinoline synthesis strategy based on oxadiazole-directed aromatic C-H coupling with alkynes and a subsequent redox-neutral C-N cyclization reaction. This labile N-O bond-based protocol has allowed the toleration of a broad range of functional groups.

The first one-pot ambient-temperature synthesis of 1,2,4-oxadiazoles from amidoximes and carboxylic acid esters

The first one-pot room-temperature protocol for the synthesis of 3,5-disubstituted-1,2,4-oxadiazoles via the condensation between amidoximes and carboxylic acid esters in superbase medium MOH/DMSO is reported. A broad spectrum of alkyl, aryl and hetaryl amidoximes and esters was examined. This reaction route provides convenient access to 1,2,4-oxadiazoles, which is highly desirable because in the light of this privileged scaffold is recognized as an important core in the design of novel therapeutic agents and high-tech materials.

Preparation, structure, and versatile reactivity of pseudocyclic benziodoxole triflate, new hypervalent iodine reagent

A new pseudocyclic triflate derivative of benziodoxole (IBA-OTf) was prepared and characterized by X-ray analysis. This highly electrophilic reagent readily reacts with various organic substrates to give the corresponding products in good yields. Furthermore, IBA-OTf can be used as a catalyst with m-chloroperoxybenzoic acid as the terminal oxidant. This journal is

A novel, one-pot, three-component synthesis of 1,2,4-oxadiazoles under microwave irradiation and solvent-free conditions

A novel synthesis of 3,5-disubstituted 1,2,4-oxadiazoles is described from a one-pot, three-component reaction between nitriles, hydroxylamine, and Meldrum's acids under microwave irradiation and solvent-free conditions in good to excellent yields. Georg

Preparation of 3,5-disubstituted 1,2,4-oxadiazoles by reactions of nitrilium salts with amide oximes

The reaction of N-alkyl- and N-arylnitrilium salts 1a,d,g,j with the amide oximes 2a-c furnished the new iminium salts 3a-k (76-93%). On heating, compounds 3a-c cyclized to salts, which were transformed with base to the 3,5-disubstituted 1,2,4-oxadiazoles 4a-c in good yields (ca. 80%).

Palladium-catalyzed N-arylation of O-methylamidoximes

Pd-catalyzed coupling of O-methylbenzamidoximes gave N-aryl O-methylbenzamidoximes using aryl halides with electron attracting or moderate electron donating groups. Under the same conditions, benzamidoxime failed to undergo coupling and O-acetylbenzamidoxime underwent cyclization to form the corresponding [1,2,4]oxadiazole.

Synthesis of 3,5-disubstituted-1,2,4-oxadiazoles using tetrabutylammonium fluoride as a mild and efficient catalyst

Tetrabutylammonium fluoride (TBAF) was found to be a mild and efficient catalyst for the synthesis of 3,5-disubstituted-1,2,4-oxadiazoles. Using 0.1 - 1.0 equivalents of TBAF in THF for 1 - 24 h at room temperature, alkanoyl- and aroyloxyamidines were converted in high yield to the corresponding 3,5-disubstituted-1,2,4-oxadiazoles. A variety of R and R′ substituents were investigated.