819-00-1Relevant articles and documents
PROCESS FOR PREPARING 3,3,3-TRIFLUOROPROPENE
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Page/Page column 11, (2010/11/03)
The invention provides a process for preparing 3,3,3-trifluoropropene (1243zf), the process comprising contacting a compound of formula CX3CH2CH2X or CX3CH=CH2, with hydrogen fluoride (HF) in the presence of a zinc/chromia catalyst, wherein each X independently is F, Cl, Br or I, provided that in the compound of formula CX3CH=CH2, at least one X is not F.
PROCESS
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Page/Page column 36, (2009/11/29)
The invention provides a process for preparing 1,1,1-trifluoro-2,3-dichloropropane (243db), which process comprises contacting 3,3,3-trifluoropropene (1243zf) with chlorine in the presence of a catalyst, wherein the catalyst comprises activated carbon, alumina and/or an oxide of a transition metal.
REACTIONS OF HALOGEN FLUORIDES. X. FLUORINATION OF CHLORINE-SUBSTITUTED ALKANES WITH BROMINE TRIFLUORIDE
Kartashov, A. V.,Chuvatkin, N. N.,Boguslavskaya, L. S.
, p. 2276 - 2278 (2007/10/02)
Bromine trifluoride in Freon 113 readily substitutes the chlorine atoms in monochloroalkanes by fluorine, while in the presence of catalytic amounts of certain Lewis acids it is also capable of substituting the chlorine atoms in polychloroalkanes with the formation of the corresponding fluorides.Additions of tin tetrachloride make it possible not only to increase the reaction rate but also to increase the selectivity of fluorination.In some cases substitution of a primary chlorine atom is accompanied by hydride transfers.