82128-66-3Relevant academic research and scientific papers
Multifunctional lanthanide-organic frameworks for fluorescent sensing, gas separation and catalysis
Liu, Xiaobin,Lin, Huan,Xiao, Zhenyu,Fan, Weidong,Huang, Ao,Wang, Rongming,Zhang, Liangliang,Sun, Daofeng
, p. 3743 - 3749 (2016)
Two lanthanide MOFs based on 3,3′-((2,3,6,7-tetramethoxyanthracene-9,10-diyl)bis(4,1-phenylene))diacrylic acid (H2LOMe), [Eu(LOMe)1.5(H2O)2]·3.5DMA·2H2O (1) and [Pr(LOMe/su
Development of a porous bifunctional metal-organic framework for cyanosilylation of aldehydes and ablation of human laryngocarcinoma cells
Zhou, Jie,Xiong, Jun-Wei,Zhao, Yu
, p. 829 - 835 (2019)
This work presents the synthesis and properties study of a new dual-functional metal-organic framework (MOF) with the chemical formula of [Cu7(nbpt)4(H2O)2(OH)4]·(DMF)5(H2O) (1,
Porous GdIII-Organic Framework as a Dual-Functional Material for Cyanosilylation of Aldehydes and Ablation of Human Liver Cancer Cells
Han, Dong,Yan, Xiu-Li,Liu, Jian
, p. 422 - 427 (2019)
Metal-organic frameworks (MOFs) have gained great attention in recent years because they could behave as multifunctional materials which combine the advances of porous solids and coordination complexes. With the aim of constructing multifunctional MOFs, i
Role of metal center and coordination environment in M-(Z)-N-((E)-pyridin-2-ylmethylene)isonicotinohydrazonate (M = LaIII, ZnII, CdII or HgII) catalyzed cyanosilylation of aldehydes
Hajiyeva, Sevinc R.,Huseynov, Fatali E.,Kopylovich, Maximilian N.,Mahmoudi, Ghodrat,Nikitina, Eugeniya V.,Prisyazhnyuk, Ekaterina D.,Shamilov, Nazim T.,Zubkov, Fedor I.
, (2021/09/07)
A series of known metal complexes, [LaL2(NO3)(H2O)2]·5H2O (1), [Zn(μ-L)(NO3)(H2O)]n (2), {[Cd2(μ-HL)(μ-L)(NO3)3(H2O)]·Hsub
Application of an Electrochemical Microflow Reactor for Cyanosilylation: Machine Learning-Assisted Exploration of Suitable Reaction Conditions for Semi-Large-Scale Synthesis
Sato, Eisuke,Fujii, Mayu,Tanaka, Hiroki,Mitsudo, Koichi,Kondo, Masaru,Takizawa, Shinobu,Sasai, Hiroaki,Washio, Takeshi,Ishikawa, Kazunori,Suga, Seiji
supporting information, p. 16035 - 16044 (2021/09/02)
Cyanosilylation of carbonyl compounds provides protected cyanohydrins, which can be converted into many kinds of compounds such as amino alcohols, amides, esters, and carboxylic acids. In particular, the use of trimethylsilyl cyanide as the sole carbon source can avoid the need for more toxic inorganic cyanides. In this paper, we describe an electrochemically initiated cyanosilylation of carbonyl compounds and its application to a microflow reactor. Furthermore, to identify suitable reaction conditions, which reflect considerations beyond simply a high yield, we demonstrate machine learning-assisted optimization. Machine learning can be used to adjust the current and flow rate at the same time and identify the conditions needed to achieve the best productivity.
An uncoordinated tertiary nitrogen based tricarboxylate calcium network with Lewis acid-base dual catalytic sites for cyanosilylation of aldehydes
Wang, Ying-Xia,Wang, Hui-Min,Meng, Pan,Song, Dong-Xia,Hou, Juan-Juan,Zhang, Xian-Ming
, p. 1740 - 1745 (2021/02/16)
The design and utilization of dual sites for synergistic catalysts has been recognised as an efficient method towards high-efficiency catalysis in the cyanosilylation of aldehydes, which gives key intermediates for the synthesis of a number of valuable na
Multinuclear transition metal-containing polyoxometalates constructed from Nb/W mixed-addendum precursors: synthesis, structures and catalytic performance
Chen, Xuenian,Li, Na,Li, Shujun,Ma, Yubin,Xiao, Wanru,Zhang, Jie,Zhao, Yue
supporting information, p. 8690 - 8695 (2021/07/02)
Four new transition metal-containing Nb/W mixed-addendum POM trimers with the formula H19[M4(H2O)x(P2W15Nb3O62)3]·m(HCOOH)·nH2O (M = Cu,x= 15,m=
n-Butyllithium as a highly efficient precatalyst for cyanosilylation of aldehydes and ketones
Kang, Zihan,Wang, Yuhong,Xu, Xiaojuan,Xue, Mingqiang,Zhang, Wenxuan,Zhou, Shuai,Zhu, Xu
supporting information, p. 7432 - 7437 (2021/09/07)
A highly efficient cyanosilylation protocol mediated by the easily availablen-BuLi with a wide range of aldehydes and ketones was developed. This protocol features excellent yields with very lown-BuLi loadings (0.01-0.05 mol%) at room temperature, solvent
Three Coordinated Organoaluminum Cation for Rapid and Selective Cyanosilylation of Carbonyls under Solvent-Free Conditions
Bhandari, Mamta,Prashanth, Billa,Rawat, Sandeep,Singh, Sanjay
, (2020/05/19)
The well-defined three coordinated electronically unsaturated cationic organoaluminum complex [({(2,6-iPr2C6H3N)P(Ph2)}2N)AlMe]+[MeB(C6F5)3]? (1), has been utilized to catalyze the cyanosilylation of aldehydes and ketones under mild and solvent-free conditions. Moreover, catalyst 1 showed high chemoselective cyanosilylation of aldehydes over ketones, nitriles and olefins. The multinuclear NMR investigations revealed that cyanosilylation proceeds via Lewis adduct formation between 1 and TMSCN thereby activating TMSCN (Si-CN bond) followed by nucleophilic attack of the carbonyl oxygen at the Si center of the activated silane and formation of the product.
Role of aromatic: Vs. aliphatic amine for the variation of structural, electrical and catalytic behaviors in a series of silver phosphonate extended hybrid solids
Rom, Tanmay,Paul, Avijit Kumar
, p. 13618 - 13634 (2020/10/26)
Four inorganic-organic hybrid silver phosphonate compounds, [Ag(C10H8N2)(H4hedp)] (1), [Ag2(C10H8N2)(H3hedp)]·2H2O (2), [C4H12N2][Ag4(H2hedp)2] (3) and [C4H12N2][Ag10(H2hedp)4(H2O)2]·2H2O (4) (H5hedp = 1-hydroxyethane-1,1-diphosphonic acid), have been pre
