82437-75-0

Basic information

• Product Name: 3-(4-METHOXY-PHENYL)-THIOPHENE
• Synonyms: 3-(4-METHOXY-PHENYL)-THIOPHENE;AKOS BAR-0369
• CAS NO: 82437-75-0
• Molecular Formula: C₁₁H₁₀OS
• Molecular Weight: 190.26
• Mol File: 82437-75-0.mol
• Article Data: 59

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 3-(4-METHOXY-PHENYL)-THIOPHENE(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(4-METHOXY-PHENYL)-THIOPHENE(82437-75-0)
• EPA Substance Registry System: 3-(4-METHOXY-PHENYL)-THIOPHENE(82437-75-0)

Safety Data

• Hazardous Substances Data: 82437-75-0(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Synthetic Communications, 19, p. 2809, 1989 DOI: 10.1080/00397918908052668

Upstream product

• 51431-73-3 1-(but-2-en-2-yl)-4-methoxybenzene 
• 872-31-1 3-Bromothiophene 
• 104-92-7 1-bromo-4-methoxy-benzene 
• 54095-29-3 2-chloro-4-(p-methoxyphenyl)thiophene 
• 82437-74-9 4-(4-methoxyphenyl)thiophene-2-carboxylic acid 
• 119405-65-1 tri-n-butyl(thien-3-yl)tin 
• 5720-07-0 4-methoxyphenylboronic acid 
• 6165-69-1 Thien-3-ylboronic acid 
• 696-62-8 para-iodoanisole 
• 104-47-2 p-methoxybenzylnitrile 
• 188290-36-0 thiophene 
• 623-12-1 4-chloromethoxybenzene 
• 10486-61-0 3-thienyl iodide 
• 17249-80-8 3-chlorothiophene 

Downstream Products

• 29886-67-7 3-(4'-Hydroxyphenyl)thiophene 
• 54095-29-3 2-chloro-4-(p-methoxyphenyl)thiophene 
• 158837-25-3 2-chloro-3-(p-methoxyphenyl)thiophene 
• 108979-05-1 3-(p-methoxyphenyl)-2-phenylthiophene 
• 62497-30-7 2,4-bis(4-methoxyphenyl)thiophene 
• 158837-31-1 5-chloro-2-iodo-3-(p-methoxyphenyl)thiophene 
• 158837-41-3 2-chloro-4-(p-methoxyphenyl)-5-phenylthiophene 
• 83125-19-3 3-(4-anisyl)-2,5-dibromothiophene 
• 1584117-43-0 7-methoxy-4,5-diphenylnaphtho[2,1-b]thiophene 
• 1452862-66-6 3-(4-methoxyphenyl)-5-(4-methylphenyl)thiophene 
• 1402570-31-3 C₁₁H₈BrIOS 
• 1330616-50-6 C₂₂H₁₈O₂S₂ 

Relevant articles and documents

Pd Nanoparticles Embedded Into MOF-808: Synthesis, Structural Characteristics, and Catalyst Properties for the Suzuki–Miyaura Coupling Reaction

Abstract: A heterogeneous single-site catalyst Pd@MOF-808 was successfully synthesized by water-based, green synthesis procedure. The catalytic experiments exhibited the Pd@MOF-808 promoted efficiently the Suzuki–Miyaura coupling reaction without the assistance of organic phosphine ligands at atmospheric pressure conditions. The catalyst also could be applied in the gram-scale synthesis of industrially anti-inflanmatory analgestic Fenbufen. Graphic Abstract: [Figure not available: see fulltext.]

Palladium Supported on Silk Fibroin for Suzuki–Miyaura Cross-Coupling Reactions

Silk fibroin supported Pd (Pd/SF) has been prepared and used as catalyst in Suzuki–Miyaura cross-coupling reactions in water/ethanol (4:1 v/v) mixture. The reactions proceed rapidly with aryl iodides and boronic acids with different electronic properties using low metal loading (0.38 mol-%). Pd/SF exhibits better recyclability compared to other biopolymer-supported Pd catalysts, up to nineteen cycles without loss of activity.

The Rational Design and Synthesis of Water-Soluble Thiourea Ligands for Recoverable Pd-Catalyzed Aerobic Aqueous Suzuki-Miyaura Reactions at Room Temperature

Eight precatalysts containing carboxylic-functionalized thiourea ligands are prepared and their activities and recyclability are evaluated in aerobic aqueous Suzuki-Miyaura reactions. A bulky monothiourea-Pd complex, functionalized with four carboxylic groups, shows the best activity and recyclability in the coupling of aryl bromides with arylboronic acids. The catalyst can be reused at least five times without any significant reduction in its catalytic activity. TEM analysis and the confirmed catalytic activity of the observed black precipitate reveal that Pd nanoparticles are formed during the reactions and are stabilized by the carboxylic-functionalized thiourea ligands.