82732-16-9

Upstream product

• 92829-83-9 1,4-dioxaspiro<4,5>decan-8-ol benzyl ether 
• 100-39-0 benzyl bromide 
• 2987-06-6 4-(benzyloxy)cyclohexanone 
• 22428-87-1 4,4-ethylenedioxycyclohexan-1-ol 
• 2859-78-1 4-Bromoveratrole 

Downstream Products

• 21104-32-5 (3aR,7aR)-3a-(3,4-Dimethoxy-phenyl)-6-hydroxy-1-methyl-octahydro-indol-2-one 
• 129920-37-2 (1R^*,2S^*,4R^*)-4-(benzyloxy)-1,2-epoxy-1-(3,4-dimethoxyphenyl)cyclohexane 
• 6023-73-0 mesembrine 
• 82732-18-1 1-methyl-3a-(3,4-dimethoxyphenyl)-6-(benzyloxy)-cis-octahydroindol-2-one 
• 82732-17-0 1-(3,4-dimethoxyphenyl)-4-(benzyloxy)-cis-bicyclo<4.2.0>octan-7-one 
• 82732-19-2 1-methyl-3a-(3,4-dimethoxyphenyl)-6-(benzyloxy)-cis-octahydroindole 
• 82769-20-8 (+/-)-6-epimesembranol 
• 82769-19-5 (+/-)-mesembranol 
• 125032-07-7 (1S^*,2R^*,5R^*)-N-<5-(benzyloxy)-2-hydroxy-2-(3,4-dimethoxyphenyl)cyclohex-1-yl>-α,α-dichloro-N-methylacetamide 
• 125032-08-8 (1S^*,5R^*)-N-<5-(benzyloxy)-2-(3,4-dimethoxyphenyl)cyclohex-2-en-1-yl>-α,α-dichloro-N-methylacetamide 
• 125032-09-9 N-<5-(benzyloxy)-2-(3,4-dimethoxyphenyl)cyclohex-1-en-1-yl>-α,α-dichloro-N-methylacetamide 
• 125032-10-2 (1S^*,5R^*)-N-<5-(benzyloxy)-2-(3,4-dimethoxyphenyl)cyclohex-2-en-1-yl>-N-methylacetamide 
• 82732-18-1 (3aR^*,6R^*,7aS^*)-6-(benzyloxy)octahydro-3a-(3,4-dimethoxyphenyl)-1-methylindol-2-one 
• 82732-19-2 (3aR^*,6R^*,7aS^*)-6-(benzyloxy)octahydro-3a-(3,4-dimethoxyphenyl)-1-methylindole 

Relevant academic research and scientific papers

Synthesis of (+/-)-Mesembranol and (+/-)-O-Methyljoubertiamine. Aza-Ring Expansion of cis-Bicyclooctanones

The Syntheses of (+/-)-mesembranol (1) and (+/-)-O-methyljoubertiamine (2) are described.Each synthesis is developed from a regio- and stereospecific heteroannelation sequence of the respective 1-arylcyclohexanes 4 and 10 to provide the 3a-aryl-cis-octahy

Radical Cyclization of N-(Cyclohex-2-enyl)-α,α-dichloroacetamides. Stereoselective Syntheses of (+/-)-Mesembranol and (+/-)-Elwesine

Stereoselective syntheses of the Sceletium alkaloid (+/-)-mesembranol (2) and the Amaryllidaceae alkaloid (+/-)-elwesine (3) have been achieved.A key step in the syntheses involves the Bu3SnH-mediated radical cyclization of the dichloroacetamides 34 and 4