834-14-0

Basic information

• Product Name: 4-METHOXYDIPHENYLMETHANE
• Synonyms: 1-Benzyl-4-methoxybenzene;Anisole, p-benzyl-;p-Benzylanisole;p-Methoxydiphenylmethane;p-Methoxyphenylphenylmethane;4-METHOXYDIPHENYLMETHANE;4-METHOXYDIPHENYLMETHANE 98%;(4-Methoxyphenyl)phenylmethane
• CAS NO: 834-14-0
• Molecular Formula: C₁₄H₁₄O
• Molecular Weight: 198.26
• Mol File: 834-14-0.mol
• Article Data: 282

Chemical Properties

• Boiling Point: 302.2°C at 760 mmHg
• Flash Point: 117.6°C
• Appearance: colorless/
• Density: 1,05 g/cm3
• Vapor Pressure: 0.0018mmHg at 25°C
• Refractive Index: 1.558
• Storage Temp.: room temp
• CAS DataBase Reference: 4-METHOXYDIPHENYLMETHANE(CAS DataBase Reference)
• NIST Chemistry Reference: 4-METHOXYDIPHENYLMETHANE(834-14-0)
• EPA Substance Registry System: 4-METHOXYDIPHENYLMETHANE(834-14-0)

Safety Data

• Hazard Codes: Xi,N
• Statements: 36/37/38-50/53-41-37/38
• Safety Statements: 26-36/37/39-61-60-39
• RIDADR: UN 3077 9 / PGIII
• WGK Germany: 3
• Hazardous Substances Data: 834-14-0(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Tetrahedron Letters, 28, p. 2387, 1987 DOI: 10.1016/S0040-4039(00)96131-8

InChI:InChI=1/C14H14O/c1-15-14-9-7-13(8-10-14)11-12-5-3-2-4-6-12/h2-10H,11H2,1H3

Upstream product

• 611-94-9 4-Methoxybenzophenone 
• 2746-25-0 p-Methoxybenzyl bromide 
• 100-44-7 benzyl chloride 
• 100-66-3 methoxybenzene 
• 38632-84-7 benzyl benzenesulfonate 
• 101-53-1 p-benzylphenol 
• 74-88-4 methyl iodide 
• 108-86-1 bromobenzene 
• 123-11-5 4-methoxy-benzaldehyde 
• 186581-53-3 diazomethane 
• 993-07-7 trimethylsilan 
• 429677-33-8 (p-anisyl)phenylmethyl cation 
• 1072-14-6 hexylsilane 
• 6485-79-6 chlorotriisopropylsilane 

Downstream Products

• 4578-79-4 2-(4-methoxyphenyl)-2-phenylacetonitrile 
• 611-94-9 4-Methoxybenzophenone 
• 101-53-1 p-benzylphenol 
• 65-85-0 benzoic acid 
• 24550-81-0 5-benzyl-2-methoxybenzoic acid 
• 5267-47-0 N-((4-methoxyphenyl)(phenyl)methyl)acetamide 
• 1192602-52-0 N-acetyl-N-(4-methoxyphenyl)benzamide 
• 1192602-53-1 C₁₆H₁₅NO₃ 
• 7472-54-0 N-(p-methoxyphenyl)benzamide 
• 7465-88-5 4-methoxy-N-phenylbenzamide 
• 722493-91-6 5-benzyl-2-methoxy-benzaldehyde 
• 1258238-50-4 C₁₅H₁₆O₂ 
• 1258238-41-3 C₂₅H₂₈O₅ 
• 1258238-51-5 C₁₆H₁₈O₃ 

Relevant articles and documents

High Ethylene Selectivity in Methanol-to-Olefin (MTO) Reaction over MOR-Zeolite Nanosheets

Precisely controlled crystal growth endows zeolites with special textural and catalytic properties. A nanosheet mordenite zeolite with a thickness of ca. 11 nm, named as MOR-NS, has been prepared using a well-designed gemini-type amphiphilic surfactant as

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Plasmon heating mediated Friedel-Crafts alkylation of anisole using supported AuNP@Nb2O5catalysts

Two different hybrid materials composed of gold nanoparticles (AuNPs) supported on either commercial niobium oxide HY 340 or mesoporous niobium oxide catalyzed the Friedel-Crafts alkylation of anisole by benzyl chloride. Excitation of the surface plasmon of the supported AuNPs allowed the reaction to occur at lower temperatures by acting as an alternative heat source. The localized heating produced via plasmon excitation permitted the acid catalyzed reaction to occur - at the Lewis acid sites on the Nb2O5support - at 80?°C while thermal-dark reactions using a conventional heat source, required temperatures of 120?°C or higher. The catalytic activity of the tested hybrid materials decreased with storage time. However, the deactivation showed to be reversible upon lyophilisation indicating that the nature of the deactivation could be due to water adsorption.

Development of highly efficient Friedel-Crafts alkylations with alcohols using heterogeneous catalysts under continuous-flow conditions

The development of Friedel-Crafts alkylations with alcohols under continuous-flow conditions using heterogeneous catalysts is reported. The reactivities and durabilities of the examined catalysts were systematically investigated, which showed that montmorillonite clay is the best catalyst for these reactions. A high turnover frequency of 9.0 × 102h?1was recorded under continuous-flow conditions, and the continuous operation was successfully maintained over one week.

Deoxygenation of tertiary and secondary alcohols with sodium borohydride, trimethylsilyl chloride, and potassium iodide in acetonitrile

The deoxygenation of tertiary and secondary alcohols to give the corresponding alkanes is conventionally performed using an organosilane and a strong acid. In this study, a deoxygenation method was developed for tertiary and secondary alcohols, using trimethylsilane and trimethylsilyl iodide generated in situ from sodium borohydride and trimethylsilyl chloride, and trimethylsilyl chloride and potassium iodide, respectively. With our method, tertiary and secondary alcohols, which provided stable carbocations, were converted into the corresponding alkanes. This paper also presents the optimization of the reaction conditions, the reaction mechanism, as well as the scope and limitations of the method.