84836-32-8

Basic information

• Product Name: 2-ethyl-1-(4-methoxyphenyl)butan-1-one
• Synonyms: 2-ethyl-1-(4-methoxyphenyl)butan-1-one
• CAS NO: 84836-32-8
• Molecular Formula: C₁₃H₁₈O₂
• Molecular Weight: 206.28
• Mol File: 84836-32-8.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 313.8°C at 760 mmHg
• Flash Point: 130.2°C
• Appearance: /
• Density: 0.975g/cm³
• Vapor Pressure: 0.000485mmHg at 25°C
• Refractive Index: 1.493
• CAS DataBase Reference: 2-ethyl-1-(4-methoxyphenyl)butan-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: 2-ethyl-1-(4-methoxyphenyl)butan-1-one(84836-32-8)
• EPA Substance Registry System: 2-ethyl-1-(4-methoxyphenyl)butan-1-one(84836-32-8)

Safety Data

• Hazardous Substances Data: 84836-32-8(Hazardous Substances Data)

Usage

InChI:InChI=1/C13H18O2/c1-4-10(5-2)13(14)11-6-8-12(15-3)9-7-11/h6-10H,4-5H2,1-3H3

Upstream product

• 100-07-2 4-methoxy-benzoyl chloride 
• 109-66-0 pentane 
• 97-96-1 2-Ethylbutyraldehyde 
• 5720-07-0 4-methoxyphenylboronic acid 
• 2736-40-5 chlorure d'acide ethyl-2 butyrique 
• 100-66-3 methoxybenzene 
• 88-09-5 2-Ethylbutanoic acid 
• 510-20-3 diethyl malonic acid 

Downstream Products

• 1352617-35-6 2-ethyl-1-(4-methoxyphenyl)but-1-enyl t-butyldimethylsilyl ether 
• 1352617-24-3 (E)-2-ethyl-1-(4-methoxyphenyl)-2-buten-1-one 
• 84836-31-7 4-[2-Ethyl-1-(4-fluoro-phenyl)-but-1-enyl]-phenol 
• 100256-47-1 2-ethyl-1-(4-hydroxy-phenyl)-butan-1-one 

Relevant articles and documents

Rapid and Direct Photocatalytic C(sp3)?H Acylation and Arylation in Flow

Herein, we report a photocatalytic procedure that enables the acylation/arylation of unfunctionalized alkyl derivatives in flow. The method exploits the ability of the decatungstate anion to act as a hydrogen atom abstractor and produce nucleophilic carbon-centered radicals that are intercepted by a nickel catalyst to ultimately forge C(sp3)?C(sp2) bonds. Owing to the intensified conditions in flow, the reaction time can be reduced from 12–48 hours to only 5–15 minutes. Finally, kinetic measurements highlight how the intensified conditions do not change the reaction mechanism but reliably speed up the overall process.

Process for the preparation of aryl ketones generating reduced amounts of toxic byproducts

An efficient, cost-effective method useful for the production of aryl ketones that minimizes the generation of toxic byproducts is disclosed. The method utilizes a metal triflate salt to catalyze the reaction between the carboxylic acid substrate and the aromatic substrate. The water generated by the reaction is collected and removed during the process.