849-83-2

Basic information

• Product Name: Peroxide, bis(4-methoxybenzoyl)
• CAS NO: 849-83-2
• Molecular Formula: C16H14O6
• Molecular Weight: 302.284
• Mol File: 849-83-2.mol
• Article Data: 13

Chemical Properties

• CAS DataBase Reference: Peroxide, bis(4-methoxybenzoyl)(CAS DataBase Reference)
• NIST Chemistry Reference: Peroxide, bis(4-methoxybenzoyl)(849-83-2)
• EPA Substance Registry System: Peroxide, bis(4-methoxybenzoyl)(849-83-2)

Safety Data

• Hazardous Substances Data: 849-83-2(Hazardous Substances Data)

Usage

General Description

Peroxide, bis(4-methoxybenzoyl) is a chemical compound with the molecular formula C16H14O6. It is a peroxide with two 4-methoxybenzoyl groups attached to the oxygen atoms, and it is often used as a radical initiator in polymerization reactions. Additionally, it has been studied as a potential photoinitiator for dental materials. Peroxide, bis(4-methoxybenzoyl) is considered to be stable when stored properly, but can decompose violently when heated or exposed to strong acids or bases. It is important to handle this chemical with caution and follow proper safety protocols when working with it in a laboratory setting.

Upstream product

• 110-86-1 pyridine 
• 7722-84-1 dihydrogen peroxide 
• 100-07-2 4-methoxy-benzoyl chloride 
• 67-64-1 acetone 
• 100-09-4 4-methoxybenzoic acid 

Downstream Products

• 3170-80-7 trichloromethyl radical 
• 33574-06-0 (4-Methoxybenzoyl)oxyl radical 
• 120547-45-7 C₁₆H₁₃O₆ 
• 67-72-1 hexachloroethane 
• 623-12-1 4-chloromethoxybenzene 
• 124-38-9 carbon dioxide 
• 21151-56-4 p-chlorophenoxymethyl chloride 
• 100-09-4 4-methoxybenzoic acid 
• 5452-06-2 2-chloroethyl 4-methoxylbenzoate 
• 60636-95-5 2-(4-methoxyphenyl)-5-phenyltetrazole 
• 940-10-3 p-methoxyperbenzoic acid 
• 7465-87-4 N-benzyl-4-methoxybenzamide 
• 2280-99-1 N-butyl-p-methoxybenzamide 

Relevant articles and documents

Aryl acyl peroxides for visible-light induced decarboxylative arylation of quinoxalin-2(1: H)-ones under additive-, metal catalyst-, and external photosensitizer-free and ambient conditions

Aryl radicals were generated for the first time from cheap and easily available aryl acyl peroxides in eco-friendly ethyl acetate under ambient conditions and visible-light illumination in the absence of any additive, metal catalyst, or external photosensitizer. The present arylation of quinoxalin-2(1H)-ones was chemo- and regioselective, and provided good access to various 3-arylquinoxalin-2(1H)-ones. This journal is

A carboxylate-assisted amination/unactivated C(sp2)-H arylation reactionviaa palladium/norbornene cooperative catalysis

This report describes a carboxylate-assisted palladium-catalysed Catellani reaction, which is compatible withortho-amination and unactivated C(sp2)-H arylation. This method was used to synthesize a series of 1-amino substituted dihydrophenanthridines, phenanthridines and 6H-benzo[c]chromenes. Based on kinetic isotope experiments, the kinetic curve proves that pivalic acid accelerates the reaction rate of unactivated C(sp2)-H activation, and thus this rate can keep up with the five membered aryl-norbornene-palladacycle (ANP) intermediate.

Uncatalyzed, on water oxygenative cleavage of inert C-N bond with concomitant 8,7-amino shift in 8-aminoquinoline derivatives

Oxygenative cleavage of an inert CAr-NH2 bond with concomitant 1,2 amine migration in 8-aminoquinoline derivatives is reported in water at room temperature. The reaction is highly atom- and step-economical as both C- and N-containing fragments of the C-N bond cleavage are incorporated into the target molecule and is effected without the need for N-oxide. The reaction is scalable to gram level, and the products are useful as electrophilic partners for coupling reactions, ligands in catalysis and bioactive compounds.