861-67-6

Basic information

• Product Name: 4-methyl-N-tritylbenzenesulfonamide
• CAS NO: 861-67-6
• Molecular Formula: C₂₆H₂₃NO₂S
• Molecular Weight: 413.5313
• Mol File: 861-67-6.mol
• Article Data: 8

Chemical Properties

• Boiling Point: 583.5°C at 760 mmHg
• Flash Point: 306.7°C
• Density: 1.201g/cm³
• Vapor Pressure: 1.32E-13mmHg at 25°C
• Refractive Index: 1.631
• CAS DataBase Reference: 4-methyl-N-tritylbenzenesulfonamide(CAS DataBase Reference)
• NIST Chemistry Reference: 4-methyl-N-tritylbenzenesulfonamide(861-67-6)
• EPA Substance Registry System: 4-methyl-N-tritylbenzenesulfonamide(861-67-6)

Safety Data

• Hazardous Substances Data: 861-67-6(Hazardous Substances Data)

Upstream product

• 519-73-3 triphenylmethane 
• 127-65-1 chloroamine-T 
• 596-43-0 bromo-triphenyl-methane 
• 55962-05-5 [N-(p-tolylsulfonyl)imino]phenyliodinane 
• 76-84-6 triphenylmethyl alcohol 
• 4104-47-6 N-sulfinyl-p-toluenesulfonamide 
• 5824-40-8 Triphenylmethylamin 
• 41085-71-6 bromamine T 
• 14309-25-2 trityl azide 
• 4083-64-1 Tosyl isocyanate 

Relevant articles and documents

Visible-light-mediated, nitrogen-centered radical amination of tertiary alkyl halides under metal-free conditions to form α-tertiary amines

A mild and operationally convenient amino-functionalization of a range of tertiary alkyl halides by reaction with iminoiodinanes (PhINNs) and I2 has been developed. According to the mechanistic experiments described within, the reaction is spec

Iron-catalyzed efficient intermolecular amination of C(sp3)-H bonds with bromamine-T as nitrene source

[Fe(N4Py)(CH3CN)](ClO4)2 can efficiently catalyze intermolecular nitrene insertion of sp3 C-H bonds with bromamine-T as the nitrene source, forming the desired tosylprotected amines with NaBr as the by-product.

Hydrous zinc halide-catalyzed aminosulfonation of hydrocarbons

Benzylic and allylic hydrocarbons are selectively converted to the corresponding sulfonamides by a ZnBr2-H2O-catalyzed reaction with PhI=NTs; saturated adamantane is aminosulfonated at the tertiary C-H bond. The Royal Society of Chemistry.