86628-50-4Relevant academic research and scientific papers
Reactions of polychlorophenyllithium compounds with electrophiles
Burukin,Vasil'ev,Struchkova,Kachala,Zlotin
, p. 964 - 969 (2005)
Polychloroaromatic compounds lithiated by BunLi in THF react with several electrophilic agents of which aldehydes and epoxides seem to be the most promising from the preparative point of view.
The Reaction of Chloromagnesium Bis(2,3,5,6-tetrachlorophenyl)copper with Butyllithium
Rahman, Mohammed T.
, p. 445 - 452 (2007/10/02)
Chloromagnesium bis(2,3,5,6-tetrachlorophenyl)copper, prepared from two equivalents of 2,3,5,6-tetrachlorphenylmagnesium chloride and one equivalent of copper(I) chloride in THF, reacts with one equivalent of butyllithium at -78 deg C to give, subsequent to derivatisation with chlorotrimethylsilane and then with acetyl chloride, (1-acetyl-2,3,5,6-tetrachlorophenyl)trimethylsilane (20percent), 1-(trimethylsilyl)-2,3,5,6-tetrachlorobenzene (17percent) and 1-acetyl-2,3,5,6-tetrachlorobenzene (34percent) along with some trace products.The formation of these products is explained on the basis of the intermediate formation of chloromagnesium bis(1-lithio-2,3,5,6-tetrachlorophenyl)copper, a functionalised cuprate reagent. - Keywords: Chloromagnesium Bis(1-lithio-2,3,5,6-tetrachlorophenyl)copper; Cuprate
