86769-18-8Relevant academic research and scientific papers
Copper-catalyzed aerobic aliphatic C-H oxygenation with hydroperoxides
Too, Pei Chui,Tnay, Ya Lin,Chiba, Shunsuke
, p. 1217 - 1225 (2013/07/26)
We report herein Cu-catalyzed aerobic oxygenation of aliphatic C-H bonds with hydroperoxides, which proceeds by 1,5-H radical shift of putative oxygen-centered radicals (O-radicals) derived from hydroperoxides followed by trapping of the resulting carboncentered radicals with molecular oxygen.
Evidence for the Formation of the Oxacyclopentenyl Cation from a Cyclopropyl Ketone
Murphy, William S.,Hantawong, Kesra
, p. 817 - 820 (2007/10/02)
On treatment with stannic chloride in nitromethane or concentrated sulphuric acid trans-2-phenylcyclopropyl phenyl ketone (1) gives the same intermediate as shown by an in situ 1H and 13C n.m.r. investigation.In concentrated sulphuric acid this intermedia
