869964-21-6

Basic information

• Product Name: 4,6-bis-tert-butyldimethylsilanyloxy-3-methyl-2-(2-oxoethyl)benzoic acid methyl ester
• Synonyms: 4,6-bis-tert-butyldimethylsilanyloxy-3-methyl-2-(2-oxoethyl)benzoic acid methyl ester
• CAS NO: 869964-21-6
• Molecular Weight: 452.739
• Mol File: 869964-21-6.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 4,6-bis-tert-butyldimethylsilanyloxy-3-methyl-2-(2-oxoethyl)benzoic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 4,6-bis-tert-butyldimethylsilanyloxy-3-methyl-2-(2-oxoethyl)benzoic acid methyl ester(869964-21-6)
• EPA Substance Registry System: 4,6-bis-tert-butyldimethylsilanyloxy-3-methyl-2-(2-oxoethyl)benzoic acid methyl ester(869964-21-6)

Safety Data

• Hazardous Substances Data: 869964-21-6(Hazardous Substances Data)

Upstream product

• 89877-54-3 2-Hydroxy-4,6-dimethoxy-3-methyl-benzoesaeure-methylester 
• 51116-93-9 3-Formyl-2-hydroxy-4,6-dimethoxy-benzoesaeuremethylester 
• 29723-28-2 methyl 2,4,6-trimethoxybenzoate 
• 864514-39-6 methyl 2-allyl-4,6-dihydroxy-3-methylbenzoate 
• 51116-92-8 methyl 4,6-dimethoxysalicylate 
• 83-30-7 acide 2,4,6-trihydroxybenzoique 
• 69739-34-0 t-butyldimethylsiyl triflate 
• 292157-65-4 4,6-dihydroxy-2-methoxycarbonylmethyl-3-methylbenzoic acid methyl ester 
• 869964-34-1 4,6-bis-tert-butyldimethylsilanyloxy-2-methoxycarbonylmethyl-3-methylbenzoic acid methyl ester 

Downstream Products

• 869964-22-7 (2R,3R)-4,6-bis-tert-butyldimethylsilanyloxy-2-hydroxy-3-methylpent-4-enyl-3-methylbenzoic acid methyl ester 
• 869964-35-2 (2R,3R)-4,6-bis-tert-butyldimethylsilanyloxy-2-(2-tert-butyldimethylsilanyloxy-3-methylpent-4-enyl)-3-methylbenzoic acid methyl ester 
• 869964-23-8 (2R,3R)-4,6-bis-tert-butyldimethylsilanyloxy-2-(2-tert-butyldimethylsilanyloxy-3-methyl-4-oxobutyl)-3-methylbenzoic acid methyl ester 

Relevant articles and documents

Synthesis of 8-desmethoxy psymberin: A putative biosynthetic intermediate towards the marine polyketide psymberin

The synthesis of a putative biosynthetic precursor of psymberin including a formal synthesis of the natural product is described. The key step towards the densely functionalized tetrahydropyran core was an enantioselective catalytic Mukaiyama aldol reacti

Total synthesis and biological evaluation of pederin, psymberin, and highly potent analogs

The potent cytotoxins pederin and psymberin have been prepared through concise synthetic routes (10 and 14 steps in the longest linear sequences, respectively) that proceed via a late-stage multicomponent approach to construct the N-acyl aminal linkages.