874-58-8

Basic information

• Product Name: Benzoyl bromide, 4-methyl-
• Synonyms: 4-Methyl-benzoylbromid;p-Toluylbromid;p-Toluylsaeure-bromid;p-toluoyl bromide;4-methyl-benzoyl bromide
• CAS NO: 874-58-8
• Molecular Formula: C8H7BrO
• Molecular Weight: 199.047
• Mol File: 874-58-8.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Benzoyl bromide, 4-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoyl bromide, 4-methyl-(874-58-8)
• EPA Substance Registry System: Benzoyl bromide, 4-methyl-(874-58-8)

Safety Data

• Hazardous Substances Data: 874-58-8(Hazardous Substances Data)

Upstream product

• 122-00-9 para-methylacetophenone 
• 201230-82-2 carbon monoxide 
• 106-38-7 para-bromotoluene 
• 104-87-0 4-methyl-benzaldehyde 
• 17264-54-9 sodium p-methylbenzoate 
• 99-94-5 p-Toluic acid 

Downstream Products

• 99-75-2 4-methyl-benzoic acid methyl ester 
• 119-61-9 benzophenone 
• 611-97-2 bis(p-methylphenyl)-methanone 
• 92-52-4 biphenyl 
• 613-33-2 (4,4'-dimethyl-1,1'-biphenyl) 
• 644-08-6 4-Methylbiphenyl 
• 134-84-9 4-Methylbenzophenone 
• 3457-48-5 1,2-di(4-methylphenyl)-1,2-ethanedione 
• 1857-74-5 2,3-diphenylbutane 
• 14161-82-1 rac-1-(4-methylphenyl)-2-phenylpropan-1-one 
• 108-88-3 toluene 
• 540-08-9 heptadecan-9-one 
• 168432-71-1 octyl p-tolyl ketone 
• 5259-72-3 cyclo-octa-1,5-diene 

Relevant articles and documents

Synthesis and Anti-Oomycete Activity of 1-Sulfonyloxy/Acyloxydihydroeugenol Derivatives

Endeavor to discover biorational natural products-based fungicides, two series (26) of novel 1-sulfonyloxy/acyloxydihydroeugenol derivatives (3a–p and 5a–j) were prepared and assessed for their fungicidal activity against P. capsici Leonian, in vitro. Res

Convenient metal-free direct oxidative amidation of aldehyde using dibromoisocyanuric acid under mild conditions

A facile method for the direct synthesis of amides from aldehydes is described. Amide bonds were synthesized by an oxidative amidation in the presence of dibromoisocyanuric acid (DBI). Treatment of aromatic and aliphatic aldehydes with dibromoisocyanuric acid generated acyl bromide intermediates, which were employed to react with a variety of secondary and primary amines to give amides. Through this reaction method, various amides were synthesized directly from aldehydes under mild conditions in high yields and short times. This facile and efficient procedure provides potential strategy for the direct synthesis of amides from aldehydes.

Solid state nuclear bromination with N-bromosuccinimide. Part 2. Experimental and theoretical studies of reactions with some substituted benzaldehydes

N-Bromosuccinimide reacts with aromatic aldehydes in the solid state to yield exclusively nuclear brominated products while a similar reaction in the solution phase produces a number of products under varied conditions. The reactivity and regioselectivity have been studied in terms of the energies of HOMO, HOMO-LUMO difference, reaction free energy, reaction conditions and crystal packing. Single crystal X-ray structural analysis of 3,4-dihydroxybenzaldehyde has been carried out. Crystal packing energies of some of the reactive and unreactive benzaldehydes indicate the importance of molecular bromine diffusion in the solid state.