877-07-6

Usage

Uses

Used in Propulsion Systems:
Hexamethylborazine is utilized as a high-energy fuel in propulsion systems, particularly rocket engines. Its high energy density and substantial energy release upon combustion make it an ideal choice for high-performance applications.
Used in Material Science:
In the field of material science, hexamethylborazine has been investigated for its potential role in boron nitride thin film deposition. This application takes advantage of its properties to create materials with high-temperature stability and exceptional mechanical characteristics.
Used in Ceramics Production:
As a precursor for boron nitride ceramics, hexamethylborazine contributes to the development of advanced ceramics with high-temperature stability and remarkable mechanical properties, making it valuable in the ceramics industry.
Safety Note:
It is important to highlight that hexamethylborazine is toxic and harmful if ingested or inhaled. Therefore, strict handling and safety measures are mandatory when working with hexamethylborazine to ensure the well-being of individuals and the environment.

Upstream product

• 17933-16-3 dibromomethylborane 
• 920-68-3 heptamethyldisilazane 
• 76875-58-6 dimethyl{(trimethylsilyl)(trimethylsiloxy)amino}borane 
• 122-56-5 tributyl borane 
• 703-86-6 2,4,6-trichloro-1,3,5-trimethylborazine 
• 75-16-1 methylmagnesium bromide 
• 18120-63-3 (4-vinylphenyl)magnesium bromide 
• 12108-70-2 tricarbonyl chromium ⁽⁰⁾ hexamethylborazine 
• 80-10-4 diphenylsilyl dichloride 
• 88916-89-6 C₂H₁₀BN 
• 124-38-9 carbon dioxide 

Downstream Products

• 34557-54-5 methane 
• 703-86-6 2,4,6-trichloro-1,3,5-trimethylborazine 
• 13061-96-6 dihydroxy-methyl-borane 
• 593-51-1 methylamine hydrochloride 
• 74-89-5 methylamine 
• 1582301-19-6 C₉H₁₈B₃MnN₃O₃⁽¹⁺⁾*C₃₂H₁₂BF₂₄^(1-) 

Relevant academic research and scientific papers

Recyclable Trifluoromethylation Reagents from Fluoroform

We present a strategy to rationally prepare CF3- transfer reagents at ambient temperature from HCF3. We demonstrate that a highly reactive CF3- adduct can be synthesized from alkali metal hydride, HCF3, and borazine Lewis acids in quantitative yield at room temperature. These nucleophilic reagents transfer CF3- to substrates without additional chemical activation, and after CF3 transfer, the free borazine is quantitatively regenerated. These features enable syntheses of popular nucleophilic, radical, and electrophilic trifluoromethylation reagents with complete recycling of the borazine Lewis acid.

COMPLEXES FOR NUCLEOPHILIC, RADICAL, AND ELECTROPHILIC POLYFLUOROALKYLATION

Disclosed herein are borazine complexes and use of the same in perfluoroalkylation reactions.

B-methyl amine borane derivatives: Synthesis, characterization, and hydrogen release

We describe the synthesis of MeH2N-BH2Me (3) and H3N-BH2Me (4) as potential hydrogen storage materials with 6.8wt-% and 8.9wt-% capacity, respectively. Compounds 3 and 4 readily release 2 equivalents of H2 at 80°C in the presence of a CoCl2 catalyst to furnish the corresponding trimerized borazine derivatives. Regeneration of 3 from its spent fuel material can be accomplished using a simple two-step process: activation with formic acid followed by reduction with LiAlH4. CSIRO 2014.

Organoborazines. Part 2. Synthesis of Alkenyltriborazines

A series of unsymmetrically B-substituted N-methyl and N-phenyl borazines R3(R2)2B3N3(R1)3 (R3=vinyl, allyl, or p-vinylphenyl; R2=methyl or phenyl; R1=methyl or phenyl) were prepared by substitution reactions of Cl3B3N3Me3 and H3B3N3Ph3 using Grignard reagents.Substituent exchange processes in these reactions were monitored by gas chromatography-mass spectrometry.These compounds were prepared in moderate yields and characterized by a combination of i.r. spectroscopy,(1)H, (13)C, and (11)B n.m.r. spectroscopy, mass spectrometry, and elemental analysis.N.m.r. evidence for the existence of mesomeric interactions of the borazines with the vinyl substituent and lack of such interactions with the p-vinylphenyl substituent was obtained.