90172-73-9

Basic information

• Product Name: Benzenecarbothioic acid, 4-fluoro-, S-phenyl ester
• CAS NO: 90172-73-9
• Molecular Formula: C13H9FOS
• Molecular Weight: 232.278
• Mol File: 90172-73-9.mol
• Article Data: 15

Chemical Properties

• CAS DataBase Reference: Benzenecarbothioic acid, 4-fluoro-, S-phenyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenecarbothioic acid, 4-fluoro-, S-phenyl ester(90172-73-9)
• EPA Substance Registry System: Benzenecarbothioic acid, 4-fluoro-, S-phenyl ester(90172-73-9)

Safety Data

• Hazardous Substances Data: 90172-73-9(Hazardous Substances Data)

Upstream product

• 459-56-3 4-fluorobenzylic alcohol 
• 108-98-5 thiophenol 
• 459-57-4 4-fluorobenzaldehyde 
• 882-33-7 diphenyldisulfane 
• 82102-37-2 9-methyl-9H-fluorene-9-carbonyl chloride 
• 460-00-4 1-Bromo-4-fluorobenzene 
• 456-06-4 4-fluorobenzoyl hydrazide 
• 591-50-4 iodobenzene 
• 6267-24-9 tris(ethylsulfanyl)methane 
• 456-22-4 4-Fluorobenzoic acid 
• 2251-76-5 2-(4-fluorophenyl)-2-oxoacetic acid 
• 403-43-0 4-fluorobenzoyl chloride 

Downstream Products

• 345-83-5 4-fluorobenzophenone 
• 345-92-6 4,4'-Difluorobenzophenone 
• 7570-96-9 2-naphthyl phenyl sulfide 
• 38700-88-8 m-chlorophenyl phenylsulfide 
• 13343-26-5 phenyl p-chlorophenyl sulfide 
• 10169-55-8 1-[4-(phenylthio)phenyl]ethan-1-one 
• 40730-41-4 methyl 4-(phenylthio)benzoate 
• 5633-57-8 1-methoxy-4-(phenylsulfanyl)benzene 
• 3699-01-2 4-tolyl phenyl sulfide 
• 139-66-2 diphenyl sulfide 
• 53451-90-4 phenyl 4-trifluoromethylphenyl sulfide 
• 7214-53-1 (E)-[2-(phenylsulfanyl)vinyl]benzene 
• 16718-12-0 2-(Phenylthio)thiophene 
• 16003-14-8 2-phenylthiofuran 

Relevant articles and documents

Rh(I)-Catalyzed Intramolecular Decarbonylation of Thioesters

Decarbonylative synthesis of thioethers from thioesters proceeds in the presence of a catalytic amount of [Rh(cod)Cl]2 (2 mol %). The protocol represents the first Rh-catalyzed decarbonylative thioetherification of thioesters to yield valuable thioethers. Notable features include the absence of phosphine ligands, inorganic bases, and other additives and excellent group tolerance to aryl chlorides and bromides that are problematic using other metals to promote decarbonylation. Gram scale synthesis, late-stage pharmaceutical derivatization, and orthogonal site-selective cross-couplings by C-S/C-Br cleavage are reported.

Cu-Catalyzed Oxidative Thioesterification of Aroylhydrazides with Disulfides

An alternative thioesterification reaction via copper-catalyzed oxidative coupling of readily available aroylhydrazides with disulfides is developed, in which oxidative expulsion of N2 overcomes the activation barrier between the carboxylic acid derivativ

Method for preparing benzoic acid-S-phenyl ester compound through cuprous catalysis

The invention discloses a method for preparing a benzoic acid-S-phenyl ester compound shown as a formula (IV) through cuprous catalysis. The preparation method comprises the following steps of: preparing a reaction product from a benzaldehyde compound shown as a formula (I), elemental sulfur shown as a formula (II) and an iodobenzene compound shown as a formula (III) by using cuprous iodide as a catalyst, tetraethylammonium bromide as an alkali and N, N-dimethylformamide as a medium, and carrying out post-treatment on the reaction product to obtain the benzoic acid-S-phenyl ester compound, wherein the formulas are described in the specification. The method is efficient in chemical agent and low in cost; and the catalytic system has wide adaptability and is suitable for large-scale production of chemical intermediates.