90841-59-1

Basic information

• Product Name: 2-(2-bromo-4,5-dimethoxyphenyl)acetaldehyde
• Synonyms: 2-(2-bromo-4,5-dimethoxyphenyl)acetaldehyde
• CAS NO: 90841-59-1
• Molecular Weight: 259.1
• Mol File: 90841-59-1.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 2-(2-bromo-4,5-dimethoxyphenyl)acetaldehyde(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(2-bromo-4,5-dimethoxyphenyl)acetaldehyde(90841-59-1)
• EPA Substance Registry System: 2-(2-bromo-4,5-dimethoxyphenyl)acetaldehyde(90841-59-1)

Safety Data

• Hazardous Substances Data: 90841-59-1(Hazardous Substances Data)

Upstream product

• 67-66-3 chloroform 
• 195383-82-5 3-(2-bromo-4,5-dimethoxy-phenyl)-propane-1,2-diol 
• 546-67-8 lead(IV) tetraacetate 
• 7417-21-2 2-(3,4-dimethoxyphenyl)ethyl alcohol 
• 289507-36-4 2-(2-bromo-4,5-dimethoxyphenyl)ethyl alcohol 
• 4697-57-8 methyl 2-(2-bromo-4,5-dimethoxyphenyl)acetate 
• 4697-62-5 6-bromohomoveratric acid 
• 5392-10-9 2-bromo-4,5-dimethoxybenzaldehyde 
• 4009-98-7 (methoxymethyl)triphenylphosphonium chloride 
• 55171-60-3 2-bromo-3,4-dimethoxybenzylaldehyde 

Downstream Products

• 1443526-64-4 (E)-ethyl 4-(2-bromo-4,5-dimethoxyphenyl)-2-methylbut-2-enoate 
• 1454883-62-5 1-(2-bromo-4,5-dimethoxybenzyl)-6,7-dimethoxyisochroman 
• 63375-81-5 2-(2-bromo-4,5-dimethoxyphenylphenyl)ethan-1-amine 
• 69327-12-4 1-bromo-2-(2-bromoethyl)-4,5-dimethoxybenzene 
• 289507-36-4 2-(2-bromo-4,5-dimethoxyphenyl)ethyl alcohol 
• 1527502-02-8 C₂₅H₂₄N₂O₄S 
• 64388-26-7 N-(2-bromo-4,5-dimethoxyphenethyl)-4-methylbenzenesulfonamide 
• 1432493-92-9 (E)-ethyl 4-(2-bromo-4,5-dimethoxyphenyl)but-2-enoate 
• 85-63-2 (R)-laudanosine 
• 5701-00-8 (R)-O-methylarmepavine 
• 50896-90-7 (-) N-norlaudanosine 
• 321669-92-5 3-[(2'-bromo-4',5'-dimethoxyphenyl)ethyl]-2α-(3',4'-dimethoxyphenethyl)-4,4,7α-trimethyl-trans-octahydro-1,3-benzoxazine 
• 321670-15-9 (1R)-N-(8-menthyl)-1-(3',4'-dimethoxyphenylethyl)-6,7-dimethoxy-1,2,3,4-tetrahydroisoquinoline 
• 321669-90-3 3-[(2'-bromo-4',5'-dimethoxyphenyl)ethyl]-2α-(3',4'-dimethoxybenzyl)-4,4,7α-trimethyl-trans-octahydro-1,3-benzoxazine 

Relevant articles and documents

Rapid Access to Azabicyclo[3.3.1]nonanes by a Tandem Diverted Tsuji–Trost Process

A three-step synthesis of the 2-azabicyclo[3.3.1]nonane ring system from simple pyrroles, employing a combined photochemical/palladium-catalysed approach is reported. Substrate scope is broad, allowing the incorporation of a wide range of functionality relevant to medicinal chemistry. Mechanistic studies demonstrate that the process occurs by acid-assisted C?N bond cleavage followed by β-hydride elimination to form a reactive diene, demonstrating that efficient control of what might be considered off-cycle reactions can result in productive tandem catalytic processes. This represents a short and versatile route to the biologically important morphan scaffold.

Enantioselective total syntheses of cedrelin A and methylated paralycolin B using Pd-catalyzed asymmetric intramolecular Friedel-Crafts allylic alkylation of phenols

We report the first enantioselective total syntheses of cedrelin A and methylated paralycolin B, wherein Pd-catalyzed asymmetric intramolecular Friedel-Crafts allylic alkylation of phenols was the key step.

CULARINE AND RELATED COMPOUNDS. V. INVESTIGATION OF THE ULLMANN

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