91638-69-6

Basic information

• Product Name: 3-methylbutyl p-tolyl sulfide
• Synonyms: 3-methylbutyl p-tolyl sulfide
• CAS NO: 91638-69-6
• Molecular Weight: 194.341
• Mol File: 91638-69-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 3-methylbutyl p-tolyl sulfide(CAS DataBase Reference)
• NIST Chemistry Reference: 3-methylbutyl p-tolyl sulfide(91638-69-6)
• EPA Substance Registry System: 3-methylbutyl p-tolyl sulfide(91638-69-6)

Safety Data

• Hazardous Substances Data: 91638-69-6(Hazardous Substances Data)

Upstream product

• 123-51-3 i-Amyl alcohol 
• 106-45-6 para-thiocresol 
• 107-82-4 i-pentyl bromide 
• 60-29-7 diethyl ether 
• 640-60-8 toluene-4-sulfonic acid phenyl ester 
• 108-88-3 toluene 
• 98215-06-6 1-lithio-1,1-bis(p-tolylthio)-methane 
• 100-99-2 triisobutylaluminum 
• 75-36-5 acetyl chloride 
• 4548-78-1 (3-methylbutyl)magnesium bromide 

Downstream Products

• 935662-19-4 (S,S^S)-1-chloro-3-methylbutyl p-tolyl sulfoxide 
• 935662-14-9 (S_S)-3-methylbutyl p-tolyl sulfoxide 

Relevant articles and documents

Iterative stereospecific reagent-controlled homologation of pinacol boronates by enantioenriched α-chloroalkyllithium reagents

Reaction of pinacol boronates with putative enantioenriched α-chloroalkyllithium species, generated in situ from homochiral α-chloroalkylsulfoxides by sulfoxide ligand exchange with t-BuLi in PhMe at -78 °C, gave chain-extended boronic ester products with generally excellent stereochemical fidelity. Iteration of this stereospecific reagent-controlled homologation (StReCH) process enabled the programmed synthesis of all four stereoisomers of a stereodiad-containing model system (4-benzyl-1,6-diphenylhexan-2-ol) with er ≥ 97:3 in all cases. Copyright