92200-02-7

Basic information

• Product Name: Benzene, 1-nitro-4-(2-phenylethoxy)-
• CAS NO: 92200-02-7
• Molecular Formula: C14H13NO3
• Molecular Weight: 243.262
• Mol File: 92200-02-7.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: Benzene, 1-nitro-4-(2-phenylethoxy)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-nitro-4-(2-phenylethoxy)-(92200-02-7)
• EPA Substance Registry System: Benzene, 1-nitro-4-(2-phenylethoxy)-(92200-02-7)

Safety Data

• Hazardous Substances Data: 92200-02-7(Hazardous Substances Data)

Upstream product

• 17376-04-4 2-phenethyl iodide 
• 1124-31-8 potassium 4-nitrophenolate 
• 40515-89-7 2-phenethoxybenzene 
• 103-63-9 1-phenyl-2-bromoethane 
• 824-78-2 4-nitrophenol sodium salt 
• 100-02-7 4-nitro-phenol 
• 100-41-4 ethylbenzene 
• 60-12-8 2-phenylethanol 
• 905718-45-8 [(4-nitrophenyl)(phenyl)iodonium trifluoromethanesulfonate] 
• 824-39-5 sodium o-nitrophenate 
• 4560-41-2 2-benzyloxynitrobenzene 
• 350-46-9 4-Fluoronitrobenzene 
• 98-95-3 nitrobenzene 

Downstream Products

• 438590-24-0 dimethyl 6-(β-phenylethyloxy)quinoline-2,4-dicarboxylate 
• 57181-84-7 4-(β-phenylethyloxy)aniline 

Relevant articles and documents

Method for synthesizing aryl benzyl ether compound

The invention discloses a method for synthesizing aryl benzyl ether compounds, which comprises the following steps: by using an iron (III) complex containing 1, 3-di-tert-butyl imidazole cations and having a molecular formula of [(tBuNCH = CHNtBu) CH] [FeBr4] as a catalyst and di-tert-butyl peroxide as an oxidant, carrying out oxidative coupling reaction on phenolic compounds and toluene compounds to synthesize the corresponding aryl benzyl ether compounds. The method is the first example for preparing the aryl benzyl ether compound through the oxidative coupling reaction of the phenolic compound and the toluene compound, which is realized by an iron-based catalyst, and has the advantages of atom economy, environmental friendliness and good substrate applicability.

Facile aromatic nucleophilic substitution (SNAr) reactions in ionic liquids: An electrophile-nucleophile dual activation by [Omim]Br for the reaction

A facile aromatic nucleophilic substitution (SNAr) reaction in recyclable [Omim]Br under relatively mild conditions has been described. An electrophile-nucleophile dual activation by [Omim]Br is also discovered based on control experiments, 1H NMR and IR spectroscopies. This chemistry provides an efficient and metal-free approach for the generation of Caryl-X (XS, N, O) bonds, many of which are significant synthetic intermediates or drugs, making this methodology attractive to both synthetic and medicinal chemistry.

Room temperature, metal-free arylation of aliphatic alcohols

Diaryliodonium salts are demonstrated as efficient arylating agents of aliphatic alcohols under metal-free conditions. The reaction proceeds at room temperature within 90 min to give alkyl aryl ethers in good to excellent yields. Aryl groups with electron