930836-30-9Relevant articles and documents
A simple and efficient synthesis of trihalomethyl and dihalonitromethyl aryl sulfones
Borys, Krzysztof M.,Korzynski, MacIej D.,Ochal, Zbigniew
, p. 6606 - 6610,5 (2012/12/12)
A method for the preparation of aryl trihalomethyl sulfones - active biocidal agents - with identical or different halogens is presented. The synthesis is based on the reaction of aryl methyl, aryl halomethyl, or aryl nitromethyl sulfones with sodium hypohalite. The method is simple in implementation, does not necessarily require the use of organic solvents, and selectively affords the products in good to excellent yields. Notably, it allows the preparation of the hitherto unknown phenyl trihalomethyl sulfone with three different halogens: fluorine, chlorine, and bromine.
Chlorodifluoromethyl phenyl sulfone: A novel non-ozone-depleting substance-based difluorocarbene reagent for O- and N-difluoromethylations
Zheng, Ji,Li, Ya,Zhang, Laijun,Hu, Jinbo,Meuzelaar, Gerrit Joost,Federsel, Hans-Juergen
, p. 5149 - 5151 (2008/09/18)
Chlorodifluoromethyl phenyl sulfone, a previously unknown compound that can be readily prepared from non-ODS-based precursors, was found to act as a robust difluorocarbene reagent for O- and N-difluoromethylations. The Royal Society of Chemistry.