934473-34-4

Upstream product

• 1588-44-9 6-phenyl-1-hexene 
• 10521-91-2 5-phenylpentan-1-ol 
• 16387-61-4 6-phenylhexanal 
• 1351992-99-8 (R)-methyl 4-(tert-butyldimethylsilyloxy)-8-phenyloctanoate 
• 1351992-98-7 (R)-methyl-4-hydroxy-8-phenyloctanoate 
• 1351993-12-8 C₂₆H₄₁NO₃Si 
• 1351993-11-7 C₂₀H₃₄O₂Si 
• 821785-90-4 (R)-8-phenyloct-1-en-4-ol 
• 90145-12-3 (S)-6-phenylhexane-1,2-diol 
• 36884-28-3 5-phenyl-1-pentanal 
• 86088-39-3 2-(5-phenylbutyl)oxirane 
• 934473-33-3 tert-butyl-dimethyl-[1-(4-phenyl-butyl)-but-3-enyloxy]-silane 
• 934473-28-6 2-(4-phenyl-butyl)-oxirane 
• 934473-29-7 tert-butyl-dimethyl-(1-oxiranylmethyl-5-phenyl-pentyloxy)-silane 

Downstream Products

• 1149764-67-9 (4S,6R)-6-(tert-butyldimethylsilanyloxy)-10-phenyldec-1-en-4-ol 
• 1149764-68-0 (4S,6R)-6-(tert-butyldimethyl silanyloxy)-10-phenyldec-1-en-4-yl acrylate 
• 1149764-69-1 (6S)-5,6-dihydro-6-[(2R)-2-(tert-butyldimethyl silanyloxy)-6-phenylhexyl]-2H-pyran-2-one 
• 1160697-63-1 tert-butyldimethyl((R)-1-((R)-oxiran-2-yl)-6-phenylhexan-2-yloxy)silane 
• 1351993-00-4 (4S,6R)-10-phenyldec-1-ene-4,6-diol 
• 397871-02-2 (6S)-5,6-dihydro-6-[(2R)-2-hydroxy-6-phenylhexyl]-2H-pyran-2-one 
• 397871-03-3 (6R)-6-[(1E,4R,6R)-4,6-dihydroxy-10-phenyldec-1-en-1-yl]-5,6-dihydro-2H-pyran-2-one 
• 934473-37-7 tert-butyl-{4-[2,2-dimethyl-6-(4-phenyl-butyl)-[1,3]dioxan-4-yl]-1-[2-(4-methoxy-benzyloxy)-ethyl]-but-2-enyloxy}-dimethyl-silane 
• 934473-35-5 9-(tert-butyl-dimethyl-silanyloxy)-1-(4-methoxy-benzyloxy)-13-phenyl-tridec-4-yne-3,7-diol 
• 934473-25-3 5-(tert-butyl-dimethyl-silanyloxy)-8-[2,2-dimethyl-6-(4-phenyl-butyl)-[1,3]dioxan-4-yl]-octa-2,6-dienoic acid methyl ester 
• 934473-36-6 6-[2,2-dimethyl-6-(4-phenyl-butyl)-[1,3]dioxan-4-yl]-1-(4-methoxy-benzyloxy)-hex-4-yn-3-ol 
• 934473-26-4 1-(4-methoxy-benzyloxy)-13-phenyl-tridec-4-yne-3,7,9-triol 
• 934473-30-0 6-[2,2-dimethyl-6-(4-phenyl-butyl)-[1,3]dioxan-4-yl]-1-(4-methoxy-benzyloxy)-hex-4-en-3-ol 
• 934473-31-1 3-(tert-butyl-dimethyl-silanyloxy)-6-[2,2-dimethyl-6-(4-phenyl-butyl)-[1,3]dioxan-4-yl]-hex-4-en-1-ol 

Relevant academic research and scientific papers

An organocatalytic route to the synthesis of (6S)-5,6-dihydro-6-[(2R)-2- hydroxy-6-phenylhexyl]-2H-pyran-2-one and ravensara lactones

An organocatalytic enantioselective synthesis of the title compounds has been achieved. The stereogenic centers were generated by the iterative use of proline catalyzed α-aminoxylations and HWE olefination of aldehydes while the lactone ring was construct

First stereoselective total synthesis of (6R)-6-[(4R,6R)-4,6-dihydroxy-10-phenyldec-1-enyl]-5,6-dihydro-2H-pyran- 2-one

A stereoselective total synthesis of (6R)-6-[(4R,6R)-4,6-dihydroxy-10-phenyldec-1-enyl]-5,6-dihydro-2H-pyran- 2-one is reported. The strategy utilizes an iterative Jacobsen hydrolytic kinetic resolution, ring opening with a chiral propargylic synthon and