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O-ethyl S-2-(4-methoxyphenyl)-2-oxoethyl carbonodithioate is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 93624-01-2 Structure
  • Basic information

    1. Product Name: O-ethyl S-2-(4-methoxyphenyl)-2-oxoethyl carbonodithioate
    2. Synonyms: O-ethyl S-2-(4-methoxyphenyl)-2-oxoethyl carbonodithioate
    3. CAS NO:93624-01-2
    4. Molecular Formula:
    5. Molecular Weight: 270.373
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 93624-01-2.mol
  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: O-ethyl S-2-(4-methoxyphenyl)-2-oxoethyl carbonodithioate(CAS DataBase Reference)
    10. NIST Chemistry Reference: O-ethyl S-2-(4-methoxyphenyl)-2-oxoethyl carbonodithioate(93624-01-2)
    11. EPA Substance Registry System: O-ethyl S-2-(4-methoxyphenyl)-2-oxoethyl carbonodithioate(93624-01-2)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 93624-01-2(Hazardous Substances Data)

93624-01-2 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 93624-01-2 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 9,3,6,2 and 4 respectively; the second part has 2 digits, 0 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 93624-01:
(7*9)+(6*3)+(5*6)+(4*2)+(3*4)+(2*0)+(1*1)=132
132 % 10 = 2
So 93624-01-2 is a valid CAS Registry Number.

93624-01-2SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 15, 2017

Revision Date: Aug 15, 2017

1.Identification

1.1 GHS Product identifier

Product name O-Ethyl S-[2-(4-methoxyphenyl)-2-oxoethyl] carbonodithioate

1.2 Other means of identification

Product number -
Other names dithiocarbonic acid S-[2-(4-methoxy-phenyl)-2-oxo-ethyl] ester O-ethyl ester

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:93624-01-2 SDS

93624-01-2Relevant articles and documents

α-Xanthylmethyl Ketones from α-Diazo ketones

López-Mendoza, Pedro,Miranda, Luis D.

, p. 3777 - 3790 (2021/07/07)

A simple and efficient method to obtain α-xanthylmethyl ketones from α-diazo ketones is described. The reaction proceeds through a protonation/nucleophilic substitution sequence in the presence of p -toluenesulfonic acid and potassium ethyl xanthogenate as the nucleophile. As α-diazo ketones can be readily synthesized from ubiquitous carboxylic acids, a broad variety of xanthates can be obtained, including examples from naturally occurring substrates.

Electrochemical reactivity of S-phenacyl-O-ethyl-xanthates in hydroalcoholic (MeOH/H2O 4:1) and anhydrous acetonitrile media

López-López, Ernesto Emmanuel,López-Jiménez, Sergio J.,Barroso-Flores, Joaquín,Rodríguez-Cárdenas, Esdrey,Tapia-Tapia, Melina,López-Téllez, Gustavo,Miranda, Luis D.,Frontana-Uribe, Bernardo A.

, (2021/04/12)

The electrochemical behavior of a series of S-phenacyl-O-ethyl-xanthates (O-ethyl-dithiocarbonate acetophenone derivatives) in hydroalcoholic (MeOH/H2O 4:1) and anhydrous media (ACN/TBAPF6) using carbon electrodes was studied. Cyclic voltammetry showed in hydroalcoholic media only two cathodic waves, whereas in ACN one anodic and two cathodic waves were present. The first cathodic wave corresponded to the reduction of the phenylketone group, whereas the first anodic was attributed to the xanthate unit. Macroelectrolysis on graphite and vitreous carbon at anodic and cathodic potentials, let us to explore the synthetic potential of this electrochemical reactions. With some compounds in hydroalcoholic media and using carbon electrodes, polymeric material was deposited on the electrode impeding the reaction; this deposit was characterized by AFM and SEM-EDS. The electroreduction on Ti electrode overcome this problem and gave the corresponding acetophenones (>95%). On the other hand, in ACN, small quantities of the dimeric 1,4-dicarbonyl compounds X-PhCOCH2CH2COPh-X (7–15%), as well as the corresponding acetophenones (ca. 50%) were isolated. Oxidation macroelectrolysis showed a very complicated transformation without synthetic value. The reaction mechanism for the reduction and the homolytic dissociation into the phenacyl radical was supported by DFT calculations.

Synthesis of pyrazolylvinyl ketones from furan derivatives

Sawengngen, Nattawut,Chalikidi, Petrakis N.,Araby, Sara,Hampel, Frank,Gmeiner, Peter,Serdyuk, Olga V.

supporting information, p. 4850 - 4855 (2019/05/24)

A new protocol for the synthesis of pyrazol-5-ylvinyl ketones, e.g. pyrazole-chalcones, employing furfuryl ketones as a triketone equivalent, has been developed. The reaction occurs under mild conditions and does not require the use of expensive materials

A simple method for the synthesis of furfuryl ketones and furylacetic acid derivatives

Chalikidi, Petrakis N.,Nevolina, Tatyana A.,Uchuskin, Maxim G.,Abaev, Vladimir T.,Butin, Alexander V.

, p. 621 - 629 (2015/10/12)

A simple preparative method has been developed for the synthesis of aryl(furfuryl) ketones, amides, and furylacetic acid esters, based on radical alkylation of furan derivatives at the α-position with O-ethyl(phenacyl)xanthogenates and phenacyl iodides in the presence of Fenton's reagent (H2O2/FeSO4·7H2O) in DMSO. The range of applicability and mechanisms for the formation of major and side products have been considered.

Flexible routes to thiophenes

Jullien, Helene,Quiclet-Sire, Beatrice,Tetart, Thomas,Zard, Samir Z.

supporting information, p. 302 - 305 (2014/01/23)

Three convergent routes to thiophenes are described, hinging on the radical addition of α-xanthyl ketones to ethyl vinyl sulfide or to vinyl pivalate. The latter route ultimately proved to be the most versatile and efficient (61-94%).

One-pot synthesis of symmetric 1,7-dicarbonyl compounds via a tandem radical addition-elimination-addition reaction

Huang, Zhongyan,Xu, Jiaxi

, p. 15114 - 15120 (2013/09/02)

A novel approach to synthesize symmetric 1,7-dicarbonyl compounds via a tandem radical addition-elimination-addition reaction of S-carbonylmethyl xanthates with allylmethylsulfone and its analogues has been developed. Radicals were produced from S-carbonylmethyl xanthates by adding dilauroyl peroxide and reacted with allylmethylsulfone or analogues to generate terminal olefins as intermediates. The excessive radicals reacted with the intermediate olefins immediately to give adducts of symmetric 1,7-dicarbonyl compounds. This is an efficient method to synthesize 1,7-dicarbonyl compounds under mild conditions. The Royal Society of Chemistry 2013.

A convergent approach to polycyclic aromatic hydrocarbons

Guignard, Raphael F.,Zard, Samir Z.

supporting information; experimental part, p. 12185 - 12187 (2011/12/15)

A new concise route to Polycyclic Aromatic Hydrocarbons (PAHs) through radical addition and cyclisation of xanthates is described. The Royal Society of Chemistry 2011.

Photochemistry of S -phenacyl xanthates

Tazhe Veetil, Aneesh,Solomek, Tomas,Ngoy, Bokolombe Pitchou,Pavlikova, Nela,Heger, Dominik,Klan, Petr

experimental part, p. 8232 - 8242 (2012/01/03)

Various synthetically readily accessible S-phenacyl xanthates are shown to undergo photoinitiated homolytic scission of the C-S bond in the primary step. The resultant fragments, phenacyl and xanthic acid radicals, recombine to form symmetrical 1,4-diketones and xanthogen disulfides, respectively, in high to moderate chemical yields in chemically inert solvents. They can also be efficiently trapped by a hydrogen-atom-donating solvent to give acetophenone and xanthic acid derivatives. The latter compound is in situ thermally converted to the corresponding alcohol in high chemical yields. S-Phenacyl xanthates could thus be utilized as synthetic precursors to the above-mentioned compounds or as photoremovable protecting groups for alcohols in which the xanthate moiety represents a photolabile linker. The photochemically released phenacyl radical fragments efficiently but reversibly add to the thiocarbonyl group of the parent xanthate molecule. The kinetics of this degenerative reversible addition-fragmentation transfer (RAFT)/macromolecular design via the interchange of xanthates (MADIX) mechanism was studied using laser flash photolysis (LFP) and density functional theory (DFT) calculations. The rate constants of the RAFT addition step, kadd ~ 7 × 108 M-1 s-1, and phenacyl radical addition to a double bond of 1,1-diphenylethylene, kadd ~ 108 M-1 s -1, in acetonitrile were experimentally determined by LFP. In addition, photoinitiation of the methyl methacrylate polymerization by S-phenacyl xanthate is demonstrated. The polydispersity index of the resulting poly(methyl methacrylate) was found to be ~1.4. We conclude that S-phenacyl xanthates can serve simultaneously as photoinitiators as well as RAFT/MADIX agents in polymerization reactions.

An expedient, flexible and convergent access to selectively protected 1,5-dicarbonyl compounds. Applications to the synthesis of 2,6-disubstituted pyridines and thiopyridines

Boivin, Jean,Carpentier, Floriane,Jrad, Rafik

, p. 1664 - 1672 (2007/10/03)

Intermolecular addition of 2-oxoalkyl radicals generated from the corresponding S-alkyl-O-ethyl dithiocarbonates on vinyl ketals afforded selectively protected 1,5-dicarbonyl compounds in good yields. These key-intermediates can be converted into a plethora of useful substances. Transformations to pyridines and thiopyridines were given as examples. Georg Thieme Verlag Stuttgart.

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