93968-39-9Relevant academic research and scientific papers
Triplet halocarbene chemistry: P-nitrophenylchlorocarbene and p-nitrophenylbromocarbene
Moss, Robert A.,Lu, Zhifeng,Sauers, Ronald R.
body text, p. 5940 - 5942 (2010/11/21)
Reactions of p-nitrophenylchlorocarbene with cumene and of p-nitrophenylbromocarbene with toluene afford C-H abstraction-recombination products that suggest the involvement of triplet arylhalocarbenes.
Elimination Reactions of Stilbene Dibromides. Dehydrobromination by Acetate, Cyanide or Chloride Ions in Dimethylformamide
Avraamides, James,Parker, Alan J.
, p. 1705 - 1717 (2007/10/02)
Rates of dehydrobromination of a series of 4-nitro- and methoxystilbene dibromides by means of acetate, cyanide or chloride ions in dimethylformamide have been measured.A product analysis was performed which indicated a strong preference for anti elimination.Probable transition state structures utilized by each of the three nucleophiles are described.Attack by the base may be at either β-hydrogen (E 2H) or Cα(E2C).The slowest reaction in with chloride ion, which also gives the highest anti/syn elimination product ratio.
