94348-26-2

Basic information

• Product Name: 2-Propen-1-one, 1-(4-methoxyphenyl)-2,3-diphenyl-, (E)-
• CAS NO: 94348-26-2
• Molecular Formula: C22H18O2
• Molecular Weight: 314.384
• Mol File: 94348-26-2.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: 2-Propen-1-one, 1-(4-methoxyphenyl)-2,3-diphenyl-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propen-1-one, 1-(4-methoxyphenyl)-2,3-diphenyl-, (E)-(94348-26-2)
• EPA Substance Registry System: 2-Propen-1-one, 1-(4-methoxyphenyl)-2,3-diphenyl-, (E)-(94348-26-2)

Safety Data

• Hazardous Substances Data: 94348-26-2(Hazardous Substances Data)

Upstream product

• 1023-17-2 4-methoxyphenyl benzyl ketone 
• 100-52-7 benzaldehyde 
• 50-00-0 formaldehyd 
• 5720-07-0 4-methoxyphenylboronic acid 
• 501-65-5 diphenyl acetylene 
• 7474-65-9 (E)-2-phenylchalcone 
• 123-11-5 4-methoxy-benzaldehyde 
• 201230-82-2 carbon monoxide 
• 100-66-3 methoxybenzene 
• 103-82-2 phenylacetic acid 

Downstream Products

• 116930-81-5 1-(p-methoxyphenyl)-2,3-diphenylprop-2-en-1-hydrazone 
• 116930-79-1 4,5-trans-1-acetyl-4,5-diphenyl-3-(p-methoxyphenyl)-4,5-dihydropyrazole 
• 116930-79-1 4,5-cis-1-acetyl-4,5-diphenyl-3-(p-methoxyphenyl)-4,5-dihydropyrazole 

Relevant articles and documents

Stereo-controlledanti-hydromagnesiation of aryl alkynes by magnesium hydrides

A concise protocol foranti-hydromagnesiation of aryl alkynes was established using 1?:?1 molar combination of sodium hydride (NaH) and magnesium iodide (MgI2) without the aid of any transition metal catalysts. The resulting alkenylmagnesium intermediates could be trapped with a series of electrophiles, thus providing facile accesses to stereochemically well-defined functionalized alkenes. Mechanistic studies by experimental and theoretical approaches imply that polar hydride addition from magnesium hydride (MgH2) is responsible for the process.

Ruthenium-catalyzed intermolecular hydroacylation of internal alkynes: The use of ceria-supported catalyst facilitates the catalyst recycling

Versatile and practical: Intermolecular hydroacylation of internal alkynes takes place in the presence of Ru catalysts together with HCO2Na and Xantphos to give the corresponding conjugated enones. Aromatic aldehydes with or without coordinatin

Synthesis of α,β-unsaturated ketones by rhodium-catalyzed carbonylative arylation of internal alkynes with arylboronic acids

The Rh-catalyzed reaction of arylboronic acids with internal alkynes under a CO atmosphere in the presence of an acid additive afforded α,β-unsaturated ketones as the major products. Hydroacylation of internal alkynes, except in the case of diaryl acetylenes, proceeded in syn fashion, yielding the E-configured isomer. A mixture of E- and Z-isomers was obtained with diphenyl acetylene. Reactions were also highly regioselective for various nonsymmetric alkynes.