999-30-4Relevant articles and documents
A novel deacylation during the amination of trifluoromethyl β-dicarbonyl compounds
Fioravanti, Stefania,Pellacani, Lucio,Ramadori, Federico,Tardella, Paolo A.
, p. 7821 - 7824 (2007)
Starting from trifluoromethyl β-dicarbonyl compounds, a rare loss of CF3CO was observed in the amination reactions performed under heterogeneous conditions using NsONHCO2Et as the aminating agent and CaO or NaH as the base, while corresponding nonfluorinated β-dicarbonyl compounds under analogous conditions give non deacylated aminated compounds. This reaction can facilitate a direct synthesis of N-substituted α-amino esters or α-amino ketones.
Titanium(IV) Complexes Based on Tridentate N,N,O Ligands - Synthesis, Structure, and Thermal Decomposition
Cherepakhin, Valeriy S.,Zaitsev, Kirill V.,Oprunenko, Yuri F.,Churakov, Andrei V.,Lermontova, Elmira Kh.,Zaitseva, Galina S.,Karlov, Sergey S.
, p. 5903 - 5912 (2015/12/24)
New tridentate N,N,O-type ligands MeN(CH2CH2NHTs)(CH2CR2OH) [Ts = tosyl; R = H, 6, (N,N,OH)H2; R = Ph, 7 (N,N,OPh)H2] were prepared. The corresponding diisopropoxide c
Alkyl 1-Chloroalkyl Carbonates: Reagents for the Synthesis of Carbamates and Protection of Amino Groups
Barcelo, Gerard,Senet, Jean-Pierre,Sennyey, Gerard,Bensoam, Jean,Loffet, Albert
, p. 627 - 632 (2007/10/02)
The synthesis of 1-chloroalkyl carbonates and their reaction with various type of amines are described.This reaction is useful for the synthesis of carbamate pesticides and for the protection of various amino groups, including amino acids.
