|
1.
1.1
IDENTIFICATION
OF
THE
SUBSTANCE/MIXTURE
AND
OF
THE
COMPANY/UNDERTAKING
Product
identifiers
Product
name
Product
Number
Brand
CAS-No.
:
:
:
:
Copper
203122
Anonymous
7440-50-8
1.2
Relevant
identified
uses
of
the
substance
or
mixture
and
uses
advised
against
Identified
uses
:
Laboratory
chemicals,
Manufacture
of
substances 2.
2.1
2.2
HAZARDS
IDENTIFICATION
Classification
of
the
substance
or
mixture
Classification
according
to
Regulation
(EC)
No
1272/2008
[EU-GHS/CLP]
Flammable
solids
(Category
1)
Acute
aquatic
toxicity
(Category
1)
Classification
according
to
EU
Directives
67/548/EEC
or
1999/45/EC
Highly
flammable.
Very
toxic
to
aquatic
organisms.
Label
elements
Labelling
according
Regulation
(EC)
No
1272/2008
[CLP]
Pictogram
Signal
word
Hazard
statement(s)
H228
H400
Precautionary
statement(s)
P210
P273
Supplemental
Hazard
Statements
Danger
Flammable
solid.
Very
toxic
to
aquatic
life.
Keep
away
from
heat/sparks/open
flames/hot
surfaces.
-
No
smoking.
Avoid
release
to
the
environment.
none
According
to
European
Directive
67/548/EEC
as
amended.
Hazard
symbol(s)
R-phrase(s)
R11
R50
S-phrase(s)
S16
S61
Highly
flammable.
Very
toxic
to
aquatic
organisms.
Keep
away
from
sources
of
ignition
-
No
smoking.
Avoid
release
to
the
environment.
Refer
to
special
instructions/
Safety
data
sheets.
2.3
3.
3.1
Other
hazards
-
none
COMPOSITION/INFORMATION
ON
INGREDIENTS
Substances
Formula
Molecular
Weight
Component
Copper
:
:
Cu
63,55
g/mol
Concentration
CAS-No.
EC-No.
7440-50-8
231-159-6
-
4.
4.1
4.2
4.3
5.
5.1
FIRST
AID
MEASURES
Description
of
first
aid
measures
General
advice
Consult
a
physician.
Show
this
safety
data
sheet
to
the
doctor
in
attendance.
If
inhaled
If
breathed
in,
move
person
into
fresh
air.
If
not
breathing,
give
artificial
respiration.
Consult
a
physician.
In
case
of
skin
contact
Wash
off
with
soap
and
plenty
of
water.
Consult
a
physician.
In
case
of
eye
contact
Flush
eyes
with
water
as
a
precaution.
If
swallowed
Do
NOT
induce
vomiting.
Never
give
anything
by
mouth
to
an
unconscious
person.
Rinse
mouth
with
water.
Consult
a
physician.
Most
important
symptoms
and
effects,
both
acute
and
delayed
Symptoms
of
systemic
copper
poisoning
may
include:
capillary
damage,
headache,
cold
sweat,
weak
pulse,
and
kidney
and
liver
damage,
central
nervous
system
excitation
followed
by
depression,
jaundice,
convulsions,
paralysis,
and
coma.
Death
may
occur
from
shock
or
renal
failure.
Chronic
copper
poisoning
is
typified
by
hepatic
cirrhosis,
brain
damage
and
demyelination,
kidney
defects,
and
copper
deposition
in
the
cornea
as
exemplified
by
humans
with
Wilson's
disease.
It
has
also
been
reported
that
copper
poisoning
has
lead
to
hemolytic
anemia
and
accelerates
arteriosclerosis.,
Damage
to
the
lungs.,
Vomiting,
Diarrhoea,
Abdominal
pain,
Blood
disorders
Indication
of
any
immediate
medical
attention
and
special
treatment
needed
no
data
available
FIREFIGHTING
MEASURES
Extinguishing
media
Suitable
extinguishing
media
Use
water
spray,
alcohol-resistant
foam,
dry
chemical
or
carbon
dioxide.
5.2
5.3
5.4
6.
6.1
6.2
6.3
6.4
7.
7.1
7.2
7.3
8.
8.1
8.2
Special
hazards
arising
from
the
substance
or
mixture
Copper
oxides
Advice
for
firefighters
Wear
self
contained
breathing
apparatus
for
fire
fighting
if
necessary.
Further
information
Use
water
spray
to
cool
unopened
containers.
ACCIDENTAL
RELEASE
MEASURES
Personal
precautions,
protective
equipment
and
emergency
procedures
Avoid
dust
formation.
Avoid
breathing
vapors,
mist
or
gas.
Ensure
adequate
ventilation.
Remove
all
sources
of
ignition.
Evacuate
personnel
to
safe
areas.
Environmental
precautions
Prevent
further
leakage
or
spillage
if
safe
to
do
so.
Do
not
let
product
enter
drains.
Discharge
into
the
environment
must
be
avoided.
Methods
and
materials
for
containment
and
cleaning
up
Sweep
up
and
shovel.
Contain
spillage,
and
then
collect
with
an
electrically
protected
vacuum
cleaner
or
by
wet-brushing
and
place
in
container
for
disposal
according
to
local
regulations
(see
section
13).
Keep
in
suitable,
closed
containers
for
disposal.
Contain
spillage,
pick
up
with
an
electrically
protected
vacuum
cleaner
or
by
wet-brushing
and
transfer
to
a
container
for
disposal
according
to
local
regulations
(see
section
13).
Reference
to
other
sections
For
disposal
see
section
13.
HANDLING
AND
STORAGE
Precautions
for
safe
handling
Avoid
formation
of
dust
and
aerosols.
Provide
appropriate
exhaust
ventilation
at
places
where
dust
is
formed.Keep
away
from
sources
of
ignition
-
No
smoking.Take
measures
to
prevent
the
build
up
of
electrostatic
charge.
Conditions
for
safe
storage,
including
any
incompatibilities
Store
in
cool
place.
Keep
container
tightly
closed
in
a
dry
and
well-ventilated
place.
Specific
end
uses
no
data
available
EXPOSURE
CONTROLS/PERSONAL
PROTECTION
Control
parameters
Components
with
workplace
control
parameters
Exposure
controls
Appropriate
engineering
controls
Handle
in
accordance
with
good
industrial
hygiene
and
safety
practice.
Wash
hands
before
breaks
and
at
the
end
of
workday.
Personal
protective
equipment
Eye/face
protection
Safety
glasses
with
side-shields
conforming
to
EN166
Use
equipment
for
eye
protection
tested
and
approved
under
appropriate
government
standards
such
as
NIOSH
(US)
or
EN
166(EU).
Skin
protection
Handle
with
gloves.
Gloves
must
be
inspected
prior
to
use.
Use
proper
glove
removal
technique
(without
touching
glove's
outer
surface)
to
avoid
skin
contact
with
this
product.
Dispose
of
contaminated
gloves
after
use
in
accordance
with
applicable
laws
and
good
laboratory
practices.
Wash
and
dry
hands.
The
selected
protective
gloves
have
to
satisfy
the
specifications
of
EU
Directive
89/686/EEC
and
the
standard
EN
374
derived
from
it.
Body
Protection
Flame
retardant
antistatic
protective
clothing,
The
type
of
protective
equipment
must
be
selected
according
to
the
concentration
and
amount
of
the
dangerous
substance
at
the
specific
workplace.
Respiratory
protection
Where
risk
assessment
shows
air-purifying
respirators
are
appropriate
use
a
full-face
particle
respirator
type
N100
(US)
or
type
P3
(EN
143)
respirator
cartridges
as
a
backup
to
engineering
controls.
If
the
respirator
is
the
sole
means
of
protection,
use
a
full-face
supplied
air
respirator.
Use
respirators
and
components
tested
and
approved
under
appropriate
government
standards
such
as
NIOSH
(US)
or
CEN
(EU).
9.
9.1
PHYSICAL
AND
CHEMICAL
PROPERTIES
Information
on
basic
physical
and
chemical
properties
a)
b)
c)
d)
e)
f)
g)
h)
Appearance
Odour
Odour
Threshold
pH
Melting
point/freezing
point
Initial
boiling
point
and
boiling
range
Flash
point
Evaporation
rate
Form:
powder
Colour:
light
red
no
data
available
no
data
available
no
data
available
Melting
point/range:
1.083,4
°C
-
lit.
2.567
°C
-
lit.
no
data
available
no
data
available
i)
Flammability
(solid,
gas)
The
substance
or
mixture
is
a
flammable
solid
with
the
category
1.
j)
k)
l)
Upper/lower
flammability
or
explosive
limits
Vapour
pressure
Vapour
density
no
data
available
no
data
available
no
data
available
m)
Relative
density
8,94
g/mL
at
25
°C
n)
o)
p)
q)
r)
s)
t)
Water
solubility
Partition
coefficient:
n-
octanol/water
Autoignition
temperature
Decomposition
temperature
Viscosity
Explosive
properties
Oxidizing
properties
no
data
available
no
data
available
no
data
available
no
data
available
no
data
available
no
data
available
no
data
available
9.2
10.
10.1
10.2
Other
safety
information
no
data
available
STABILITY
AND
REACTIVITY
Reactivity
no
data
available
Chemical
stability
no
data
available
10.3
10.4
10.5
10.6
11.
11.1
Possibility
of
hazardous
reactions
no
data
available
Conditions
to
avoid
Heat,
flames
and
sparks.
Extremes
of
temperature
and
direct
sunlight.
Incompatible
materials
Strong
acids,
Strong
oxidizing
agents,
Acid
chlorides,
Halogens
Hazardous
decomposition
products
Other
decomposition
products
-
no
data
available
TOXICOLOGICAL
INFORMATION
Information
on
toxicological
effects
Acute
toxicity
LD50
Intraperitoneal
-
mouse
-
3,5
mg/kg
Skin
corrosion/irritation
May
irritate
skin.
Serious
eye
damage/eye
irritation
May
irritate
eyes.
Respiratory
or
skin
sensitization
no
data
available
Germ
cell
mutagenicity
no
data
available
Carcinogenicity
IARC:
No
component
of
this
product
present
at
levels
greater
than
or
equal
to
0.1%
is
identified
as
probable,
possible
or
confirmed
human
carcinogen
by
IARC.
Reproductive
toxicity
no
data
available
Specific
target
organ
toxicity
-
single
exposure
May
cause
respiratory
irritation.
Specific
target
organ
toxicity
-
repeated
exposure
no
data
available
Aspiration
hazard
no
data
available
Potential
health
effects
Inhalation
Ingestion
Skin
Eyes
May
be
harmful
if
inhaled.
May
cause
respiratory
tract
irritation.
May
be
harmful
if
swallowed.
May
be
harmful
if
absorbed
through
skin.
May
cause
skin
irritation.
May
cause
eye
irritation.
Signs
and
Symptoms
of
Exposure
Symptoms
of
systemic
copper
poisoning
may
include:
capillary
damage,
headache,
cold
sweat,
weak
pulse,
and
kidney
and
liver
damage,
central
nervous
system
excitation
followed
by
depression,
jaundice,
convulsions,
paralysis,
and
coma.
Death
may
occur
from
shock
or
renal
failure.
Chronic
copper
poisoning
is
typified
by
hepatic
cirrhosis,
brain
damage
and
demyelination,
kidney
defects,
and
copper
deposition
in
the
cornea
as
exemplified
by
humans
with
Wilson's
disease.
It
has
also
been
reported
that
copper
poisoning
has
lead
to
hemolytic
anemia
and
accelerates
arteriosclerosis.,
Damage
to
the
lungs.,
Vomiting,
Diarrhoea,
Abdominal
pain,
Blood
disorders
Additional
Information
RTECS:
GL5325000
12.
12.1
ECOLOGICAL
INFORMATION
Toxicity
Toxicity
to
fish
Toxicity
to
daphnia
and
mortality
LOEC
-
Oncorhynchus
mykiss
(rainbow
trout)
-
0,022
mg/l
-
96
h
mortality
NOEC
-
Daphnia
-
0,004
mg/l
-
24
h
other
aquatic
invertebrates
EC50
-
Daphnia
magna
(Water
flea)
-
0,04
-
0,05
mg/l
-
48
h
12.2
12.3
Persistence
and
degradability
no
data
available
Bioaccumulative
potential
Bioaccumulation
Cyprinus
carpio
(Carp)
-
40
d
-200
mg/l
Bioconcentration
factor
(BCF):
108
12.4
12.5
12.6
13.
13.1
14.
14.1
Mobility
in
soil
no
data
available
Results
of
PBT
and
vPvB
assessment
no
data
available
Other
adverse
effects
Very
toxic
to
aquatic
life
with
long
lasting
effects.
Avoid
release
to
the
environment.
DISPOSAL
CONSIDERATIONS
Waste
treatment
methods
Product
Burn
in
a
chemical
incinerator
equipped
with
an
afterburner
and
scrubber
but
exert
extra
care
in
igniting
as
this
material
is
highly
flammable.
Offer
surplus
and
non-recyclable
solutions
to
a
licensed
disposal
company.
Contaminated
packaging
Dispose
of
as
unused
product.
TRANSPORT
INFORMATION
UN
number
14.2
ADR/RID:
3089
UN
proper
shipping
name
IMDG:
3089
IATA:
3089
ADR/RID:
IMDG:
IATA:
METAL
POWDER,
FLAMMABLE,
N.O.S.
METAL
POWDER,
FLAMMABLE,
N.O.S.
Metal
powder,
flammable,
n.o.s.
14.3
Transport
hazard
class(es)
14.4
14.5
14.6
15.
ADR/RID:
4.1
Packaging
group
ADR/RID:
II
Environmental
hazards
ADR/RID:
no
Special
precautions
for
user
no
data
available
REGULATORY
INFORMATION
IMDG:
4.1
IMDG:
II
IMDG
Marine
pollutant:
no
IATA:
4.1
IATA:
II
IATA:
no
This
safety
datasheet
complies
with
the
requirements
of
Regulation
(EC)
No.
1907/2006.
15.1
15.2
Safety,
health
and
environmental
regulations/legislation
specific
for
the
substance
or
mixture
no
data
available
Chemical
Safety
Assessment
no
data
available
16.
OTHER
INFORMATION
Further
information
The above information is believed to be correct but does not purport to be all inclusive and
shall be used only as a guide. The information this document is based on the resent state
of our knowledge and is applicable to the product with regard to appropriate safety precautions.
It does not represent any guarantee of the properties of the product. Lookchem shall not be
held liable for any damage resulting from handling or from contact with the above product.
See reverse side of invoice or packing slip for additional terms and conditions of sale.
| 
Copper
China (Mainland)] 
Assessed
Assessed
Assessed
Assessed
Assessed
Assessed
Assessed
Assessed
Assessed
Assessed
Assessed
Assessed
Premium
United States] 
Premium
Premium
Premium