3-Méthyl 1,1-bis(triméthylsiloxy) 1,3-butadiène et 4-triméthylsilyl 3-méthyl 2-butènoate de triméthylsilyle: préparations et réactions avec le benzaldéhyde
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Add time:07/21/2019 Source:sciencedirect.com
The regioselectivity of the reaction between benzaldehyde and the silylketene acetal prepared from trimethylsilylsenecioate is studied as a function of the catalyst used. CsF leads exclusively to the “branched” product whereas TiCl4 gives the required “linear” hydroxy acid.
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