(2S,6S,8S)-2,8-Dimethyl-1,7-dioxaspiro[5.5]undecane: A natural spiroacetal lacking anomeric stabilisation

Add time:07/19/2019    Source:sciencedirect.com

The absolute stereochemistry of the non-anomerically stabilised spiroacetal, (Z,Z)-2,8-dimethyl-1,7-dioxaspiro[5.5]undecane, 4 which is a significant component of the pheromonal gland secretion of the cucumber fly (Bactrocera cucumis French) is shown to be (2S,6S,8S) by synthesis of its enantiomer, and chiral gas chromatographic analyses.

We also recommend Trading Suppliers and Manufacturers of (6S,2S)-Diaminopimelic acid (cas 14289-34-0). Pls Click Website Link as below: cas 14289-34-0 suppliers

Prev:Enantiospecific synthesis of (1S,2S,5R,6S)-2-aminobicyclo[3.1.0]hexane-2,6-dicarboxylic acid by a modified Corey-Link reaction
Next:Synthesis of enantiopure 6-methoxy-2-Naphthylglycolic acid (cas 14289-44-2) and its application as a resolving agent)