Direct conversion of tert-butyl 2-hydroxyalkyl sulfides to 1,3-oxathiolanes
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Add time:07/18/2019 Source:sciencedirect.com
tert-Butyl 2-hydroxyalkyl sulfides, prepared by reaction of epoxides with 2-methylpropane-2-thiol, are converted directly to 1,3-oxathiolanes upon treatment with pivalaldehyde and boron trifluoride diethyl etherate in the presence of thioanisole.
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