Excimer versus TICT state formation in polar solutions of methyl 4-(N,N-dimethylamino)benzoate
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Add time:07/24/2019 Source:sciencedirect.com
The fluorescence properties of methyl 4-(N,N-dimethylamino)benzoate in a variety of solvents are reported. “Normal” fluorescence from a distribution of excited solute/solvent arrangements is observed in most solvents. Additionally, in acetonitrile, a longer wavelength fluorescence band is observed which is attributed to excited dimer fluorescence. It is proposed that the excited dimer is formed by direct excitation from the ground state.
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